We study the self-diffusion coefficient and viscosity of a water-glycerol mixture for several glycerol molar fractions as a function of temperature well inside the metastable supercooled regime. We perform NMR experiments and verify that the system has at different concentration a fragile-to-strong crossover accompanied by the violation of the Stokes-Einstein relation. We observe that the crossover temperature depends on the water amount. Studying the fractional representation of the Stokes-Einstein relation, we find that in these systems dynamical arrest does not exhibit criticality and the transport parameters have a universal behavior.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1063/1.4939087 | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!