Questioning Antiferromagnetic Ordering in the Expanded Metal, Li(NH3)4: A Lack of Evidence from μSR.

J Phys Chem Lett

Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, United Kingdom.

Published: October 2015

AI Article Synopsis

  • The study investigates the behavior of muons in the solid forms of Li(NH3)4, revealing no significant changes in muon depolarization at temperatures below 25 K, challenging current beliefs about antiferromagnetic ordering.
  • These findings align with recent neutron diffraction data, suggesting that previous interpretations of the material's magnetic properties may need revision.
  • In the higher temperature phase (82-89 K), noticeable changes in muon behavior are observed, indicating the beginning of structural movement before the substance undergoes melting.

Article Abstract

We present the results of a muon spin relaxation study of the solid phases of the expanded metal, Li(NH3)4. No discernible change in muon depolarization dynamics is witnessed in the lowest temperature phase (≤25 K) of Li(NH3)4, thus suggesting that the prevailing view of antiferromagnetic ordering is incorrect. This is consistent with the most recent neutron diffraction data. Discernible differences in muon behavior are reported for the highest temperature phase of Li(NH3)4 (82-89 K), attributed to the onset of structural dynamics prior to melting.

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http://dx.doi.org/10.1021/acs.jpclett.5b01380DOI Listing

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