The interface between a nominal In2S3 buffer and a Cu(In,Ga)Se2 (CIGSe) thin-film solar cell absorber was investigated by direct and inverse photoemission to determine the interfacial electronic structure. On the basis of a previously reported heavy intermixing at the interface (S diffuses into the absorber; Cu diffuses into the buffer; and Na diffuses through it), we determine here the band alignment at the interface. The results suggest that the pronounced intermixing at the In2S3/CIGSe interface leads to a favorable electronic band alignment, necessary for high-efficiency solar cell devices.
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http://dx.doi.org/10.1021/acsami.5b10614 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Republic of Korea.
Organic solar cells (OSCs) have recently achieved efficiencies of >20% in single-junction unit cells owing to rapid advancements in materials and device technologies. Large-area OSCs face several challenges that adversely affect their efficiency compared to small unit cells. These challenges include increased resistance loads derived from their larger dimensions, as well as limitations related to morphology, miscibility, and crystallinity.
View Article and Find Full Text PDFMXenes, a rapidly emerging class of 2D transition metal carbides, nitrides, and carbonitrides, have attracted significant attention for their outstanding properties, including high electrical conductivity, tunable work function, and solution processability. These characteristics have made MXenes highly versatile and widely adopted in the next generation of optoelectronic devices, such as perovskite and organic solar cells. However, their integration into silicon-based optoelectronic devices remains relatively underexplored, despite silicon's dominance in the semiconductor industry.
View Article and Find Full Text PDFSci Rep
January 2025
ENET Centre, VSB-Technical University of Ostrava, Ostrava, 708 00, Czech Republic.
Identifying the parameters of a solar photovoltaic (PV) model optimally, is necessary for simulation, performance assessment, and design verification. However, precise PV cell modelling is critical for design due to many critical factors, such as inherent nonlinearity, existing complexity, and a wide range of model parameters. Although different researchers have recently proposed several effective techniques for solar PV system parameter identification, it is still an interesting challenge for researchers to enhance the accuracy of the PV system modelling.
View Article and Find Full Text PDFOccup Med (Lond)
January 2025
Institute of Occupational Medicine, Edinburgh EH14 4AP, UK.
Background: Occupational exposure to solar ultraviolet (UV) is known to cause malignant melanoma (MM) and non-melanoma skin cancer (NMSC). However, knowledge of the causal associations has developed erratically.
Aims: This review aims to identify when it was accepted that workplace solar UV exposure could cause skin cancer and when it was recognized that there was a risk for outdoor workers in Britain, identifying the steps employers should have taken to protect their workers.
Nat Commun
January 2025
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, School of Materials Science and Engineering, Hebei University of Technology, Tianjin, China.
Interfacial trap-assisted nonradiative recombination hampers the development of metal halide perovskite solar cells (PSCs). Herein, we report a rationally designed universal passivator to realize highly efficient and stable single junction and tandem PSCs. Multiple defects are simultaneously passivated by the synergistic effect of anion and cation.
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