AI Article Synopsis

  • A study in Doñana National Park, Southern Spain, investigated high arsenic levels in groundwater and drinking ponds through surface and groundwater sampling, revealing concentrations as high as 302 μg/L.
  • Analysis showed that arsenic mobilization is linked to the presence of iron (Fe) in sediments, with organic matter contributing to the release of arsenic from iron oxides, while algae metabolism affects arsenic concentrations in surface water.
  • Findings indicated that variations in pH and alkalinity due to algae activity and changes in redox conditions influenced both surface and groundwater arsenic levels, highlighting complex interactions in this ecosystem.

Article Abstract

A study has been performed to explore the origin, spatiotemporal behaviour and mobilisation mechanism of the elevated arsenic (As) concentrations found in ground water and drinking ponds of the Doñana National Park, Southern Spain. At a larger scale, 13 piezometers and surface water samples of about 50 artificial drinking ponds and freshwater lagoons throughout the National Park were collected and analysed for major ions, metals and trace elements. At a smaller scale, 5 locations were equipped with piezometers and groundwater was sampled up to 4 times for ambient parameters, major ions, metals, trace elements and iron (Fe) speciation. As was analysed for inorganic and organic speciation. Undisturbed sediment samples were analysed for physical parameters, mineralogy, geochemistry as well as As species. Sediment analyses yielded total As between 0.1 and 18 mg/kg and are not correlated with As concentration in water. Results of the surface- and groundwater sampling revealed elevated concentration of As up to 302 μg/L within a restricted area of the National Park. Results of groundwater sampling reveals strong correlation of As with Fe(2+) pointing to As mobilisation due to reductive dissolution of hydroferric oxides (HFO) in areas of locally elevated amounts of organic matter within the sediments. High As concentrations in surface water ponds are correlated with elevated alkalinity and pH attributed to algae metabolism, leading to As desorption from HFO. The algae metabolism is responsible for the presence of methylated arsenic species in surface water, in contrast to ground water in which only inorganic As species was found. Temporal variations in surface water and groundwater are also related to changes in pH and alkalinity as a result of enhanced algae metabolism in surface water or related to changes in the redox level in the case of groundwater.

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http://dx.doi.org/10.1016/j.scitotenv.2015.11.138DOI Listing

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