We report the essential condition for three-photon electromagnetically induced absorption (TPEIA) in a Doppler-broadened ladder-type atomic system. When the two coupling lasers operate at different frequencies, we observed Doppler-free TPEIA resonance at a counterintuitive frequency, which is the almost half-frequency detuning of the frequency difference between the two coupling fields. Considering three-photon coherence in a Doppler-broadened ladder-type three-level atomic system, the TPEIA due to the atomic group of non-zero velocity was in good agreement with the calculated TPEIA spectrum under the one-photon resonance condition of all three optical fields. From the results, we found that an atomic group with a proper velocity for ladder-type TPEIA should satisfy the one-photon resonances of all three optical fields.
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http://dx.doi.org/10.1364/OE.23.031574 | DOI Listing |
Nanomicro Lett
January 2025
Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing, 100191, People's Republic of China.
The proliferation of wearable biodevices has boosted the development of soft, innovative, and multifunctional materials for human health monitoring. The integration of wearable sensors with intelligent systems is an overwhelming tendency, providing powerful tools for remote health monitoring and personal health management. Among many candidates, two-dimensional (2D) materials stand out due to several exotic mechanical, electrical, optical, and chemical properties that can be efficiently integrated into atomic-thin films.
View Article and Find Full Text PDFNanoscale
January 2025
School of Chemistry & Chemical Engineering, School of Materials Science and Engineering and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Department of Chemistry and Center for Atomic Engineering of Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of the Ministry of Education, Anhui University, Hefei, 230601, China.
Atomically precise nanoclusters (NCs) can serve as an excellent platform for a comprehensive understanding of structure-property relationships. Herein, three structurally similar Cu NCs (Cu-1, Cu-2 and Cu-3) have been prepared for the photocatalytic phenylacetylene self-coupling reaction. It was found that Cu-1 NC achieved the highest turnover number (TON) of 524.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan.
The quantum-electrodynamic non-adiabatic emission (QED-NAE) is a type of radiatively assisted vibronic de-excitation due to electromagnetic vacuum fluctuations on non-adiabatic processes. Building on our previous work [Tsai et al., J.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Department of Physics, Wesleyan University, Middletown, Connecticut 06459, USA.
Phase change materials such as Ge2Sb2Te5 (GST) are ideal candidates for next-generation, non-volatile, solid-state memory due to the ability to retain binary data in the amorphous and crystal phases and rapidly transition between these phases to write/erase information. Thus, there is wide interest in using molecular modeling to study GST. Recently, a Gaussian Approximation Potential (GAP) was trained for GST to reproduce Density Functional Theory (DFT) energies and forces at a fraction of the computational cost [Zhou et al.
View Article and Find Full Text PDFAbsolute line strength measurements of hydroperoxyl (HO2) radical in the OO-stretching (ν3) fundamental band have been performed by means of mid-infrared time-resolved dual-comb spectroscopy. By employing two sets of dual-comb spectrometers, high-resolution time-resolved spectra of HO2 and HCl, formed in the photolysis reaction system of Cl2/CH3OH/O2, could be, respectively, measured near 1123 and 3059 cm-1. With kinetic simulations, spectral analysis of both HO2 and HCl, as well as the accurate line strength of the HCl R(9) transition at 3059.
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