In this paper, a photochromic electret for light energy harvesting is proposed and discussed. Such electret directly converts the photon energy into electric energy thanks to a polarization modulation caused by the photochromic reaction, which leads to a change in dipole moment. Theoretical concepts on which the photochromic electret is based are considered with an estimation of the effectiveness as a function of material properties. Finally, an electret based on a photochromic diarylethene is shown with the photoelectric characterization as a proof of concept device.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/jz2014506 | DOI Listing |
Nanoscale
July 2023
Institut national de la recherche scientifique (INRS), Centre Énergie Matériaux Télécommunications, 1650 Boul. Lionel Boulet, Varennes J3X 1S2, Canada.
In the past decades, neuromorphic computing has attracted the interest of the scientific community due to its potential to circumvent the von Neumann bottleneck. Organic materials, owing to their fine tunablility and their ability to be used in multilevel memories, represent a promising class of materials to fabricate neuromorphic devices with the key requirement of operation with synaptic weight. In this review, recent studies of organic multilevel memory are presented.
View Article and Find Full Text PDFJ Am Chem Soc
September 2022
Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China.
Herein, we report robust π-conjugated radical cations resulting from the oxidation of hexabenzoperylene (HBP) derivatives, HBP-B and HBP-H, which have butyl and hexyl groups, respectively, attached to the same twisted double helicene π-backbone. The radical cation of HBP-B was successfully crystallized in the form of hexafluorophosphate, which exhibited conductivity as high as 1.32 ± 0.
View Article and Find Full Text PDFNanoscale
April 2019
Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China.
Here, we developed a novel organic semiconductor of 2,7-di(anthracen-2-yl)naphthalene (2,7-DAN), which not only exhibits outstanding hole-transport with a mobility of 3.3 cm2 V-1 s-1 but also shows a high photoresponsivity of 8000 A W-1 with detectivity as high as 1.2 × 1014 Jones.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2012
Center for Nano Science and Technology @PoliMi, Istituto Italiano di Tecnologia , via G. Pascoli 70/3, 20133 Milano, Italy.
In this paper, a photochromic electret for light energy harvesting is proposed and discussed. Such electret directly converts the photon energy into electric energy thanks to a polarization modulation caused by the photochromic reaction, which leads to a change in dipole moment. Theoretical concepts on which the photochromic electret is based are considered with an estimation of the effectiveness as a function of material properties.
View Article and Find Full Text PDFThe combined action of electric field (105-107 V x m-1) and light (380-580 nm, 80 W x m-2) activating the photoenergetic reaction of bacteriorhodopsin (BR) in dry films of purple membranes from Halobacterium halobium was studied. A new stimulating effect of the field on the BR412 intermediate accumulation in the normal photochromic cycle of BR570 has been observed. The formation of the product BR412 is supposed to be accompanied by specific rearrangements of certain charged, polar and polarizable groups in the BR pigment-protein matrix.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!