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Polyhydroxy starch with abundant hydroxyls and a unique structure enables uniform Zn deposition.

Chem Commun (Camb)

January 2025

Laboratory of Advanced Materials, Aqueous Batteries Center, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200433, China.

Zinc metal is a promising anode material for zinc-ion batteries (ZIBs), but severe side reactions and dendrite formation hinder its commercialization. In this study, starch is introduced into the ZnSO electrolyte for stabilizing the Zn anode. With abundant hydroxyl groups, starch can reconstruct the H-bond system in the electrolyte, suppressing side reactions.

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