Selective desorption of high-purity (6,5) SWCNTs from hydrogels through surfactant modulation.

Chem Commun (Camb)

Department of Chemical Engineering, University of Florida, Gainesville, Florida 32611, USA. and Department of Materials Science & Engineering, University of Florida, Gainesville, Florida 32611, USA.

Published: February 2016

Selective desorption of (6,5) single-wall carbon nanotubes from hydrogels only occurs at specific co-surfactant ratios. High-purity fractions are obtained at this ratio even with long elution times and different total co-surfactant concentrations. These results suggest that each (n,m) type forms a thermodynamically-stable surfactant structure in the co-surfactant solution, enabling high-fidelity separations in a single column.

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Source
http://dx.doi.org/10.1039/c5cc08530fDOI Listing

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