Rh(III)-Catalyzed C7-Thiolation and Selenation of Indolines. | LitMetric

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Rh(III)-Catalyzed C7-Thiolation and Selenation of Indolines. | LitMetric

Rh(III)-Catalyzed C7-Thiolation and Selenation of Indolines.

Wucheng Xie Bin Li Baiquan Wang

J Org Chem

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , Shanghai 200032, China.

Published: January 2016

The rhodium(III)-catalyzed intermolecular C7-thiolation and selenation of indolines with disulfides and diselenides were developed. This protocol relies on the use of a removable pyrimidyl directing group to access valuable C-7 functionalized indoline scaffolds with ample substrate scope and broad functional group tolerance.

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http://dx.doi.org/10.1021/acs.joc.5b01943	DOI Listing

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