The conventional approach to the turbulent energy cascade, based on Richardson-Kolmogorov phenomenology, ignores the topology of emerging vortices, which is related to the helicity of the turbulent flow. It is generally believed that helicity can play a significant role in turbulent systems, e.g., supporting the generation of large-scale magnetic fields, but its impact on the energy cascade to small scales has never been observed. We suggest, for the first time, a generalized phenomenology for isotropic turbulence with an arbitrary spectral distribution of the helicity. We discuss various scenarios of direct turbulent cascades with new helicity effect, which can be interpreted as a hindering of the spectral energy transfer. Therefore, the energy is accumulated and redistributed so that the efficiency of nonlinear interactions will be sufficient to provide a constant energy flux. We confirm our phenomenology by high Reynolds number numerical simulations based on a shell model of helical turbulence. The energy in our model is injected at a certain large scale only, whereas the source of helicity is distributed over all scales. In particular, we found that the helical bottleneck effect can appear in the inertial interval of the energy spectrum.
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http://dx.doi.org/10.1103/PhysRevLett.115.234501 | DOI Listing |
ACS Cent Sci
January 2025
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China.
Multicomponent reactions (MCRs), highly sought-after methods to produce atom-, step-, and energy-economic organic syntheses, have been developed extensively. However, catalytic asymmetric MCRs, especially those involving radical species, remain largely unexplored owing to the difficulty in stereoselectively regulating the extraordinarily high reactivity of open-shell radical species. Herein, we report a conceptually novel catalytic asymmetric three-component radical cascade reaction of readily accessible glycine esters, α-bromo carbonyl compounds and 2-vinylcyclopropyl ketones via synergistic photoredox/Brønsted acid catalysis, in which three sequential C-C (σ/π/σ) bond-forming events occurred through a radical addition/ring-opening/radical-radical coupling protocol, affording an array of valuable enantioenriched unnatural α-amino acid derivatives bearing two contiguous stereogenic centers and an alkene moiety in moderate to good yield with high diastereoselectivity, excellent enantioselectivity and good -dominated geometry under mild reaction conditions.
View Article and Find Full Text PDFAdv Mater
January 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China.
Nanomagnetism may enable electrical conductivity and Seebeck coefficient to be decoupled and can potentially lead to remarkable enhancements in thermoelectric (TE) performance, however, their physical mechanisms have not been explored. Herein, it is shown that the nanomagnetism from Fe and FeO nanoparticles embedded in BiSbTe/epoxy flexible films can lead to the carriers splitting into spin-up and spin-down conductive branches with different resistances and mobilities due to the exchange interaction between the spin of carriers and the nanomagnetism. The double-resistance conduction of carriers may well explain the decoupling of electrical conductivity and Seebeck coefficient and their simultaneous enhancements in the thermo-electro-magnetic flexible films.
View Article and Find Full Text PDFPlant Physiol Biochem
January 2025
College of Food Science and Engineering, Bohai University, 121013, Jinzhou, PR China; National & Local Joint Engineering Research Center of Storage, Processing and Safety Control Technology for Fresh Agricultural and Aquatic Products, 121013, Jinzhou, PR China. Electronic address:
Significant losses of vegetables and fruits occur at multiple stages, including harvest, sorting, storage, and transportation, primarily due to mechanical damage, pathogen invasion, and the natural process of senescence. To mitigate postharvest decay and maintain superior quality of produce, conventional techniques such as low temperature storage and synthetic fungicide treatment are widely employed. Acibenzolar-S-methyl (ASM), an effective plant resistance inducers, has demonstrated its efficacy in protecting against a diverse range of fungal and bacterial pathogens.
View Article and Find Full Text PDFEnviron Manage
January 2025
TECNALIA Research & Innovation, Basque Research and Technology Alliance (BRTA), Energy, climate, and urban transition, Parque Tecnológico de Bizkaia, Derio, Spain.
The extent and timescale of climate change impacts remain uncertain, including global temperature increase, sea level rise, and more frequent and intense extreme events. Uncertainties are compounded by cascading effects. Nevertheless, decision-makers must take action.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Faculty of Textile Technology, University of Zagreb, Prilaz baruna Filipovića 28 a, 10000 Zagreb, Croatia.
This research follows the principles of circular economy through the zero waste concept and cascade approach performed in two steps. Our paper focuses on the first step and explores the characteristics of developed biocomposite materials made from a biodegradable poly(lactic acid) polymer (PLA) reinforced with natural fibers isolated from the second generation of biomass (agricultural biomass and weeds). Two plants, L.
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