Low-Temperature in Situ Growth of Graphene on Metallic Substrates and Its Application in Anticorrosion.

ACS Appl Mater Interfaces

Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts &Telecommunications, Nanjing 210046, China.

Published: January 2016

Metal or alloy corrosion brings about huge economic cost annually, which is becoming one area of growing concern in various industries, being in bulk state or nanoscale range. Here, single layer or few layers of graphene are deposited on various metallic substrates directly at a low temperature down to 400 °C. These substrates can be varied from hundreds-micrometer bulk metallic or alloy foils to tens of nanometer nanofibers (NFs). Corrosion analysis reveals that both graphene-grown steel sheets and NFs have reduced the corrosion rate of up to ten times lower than that of their bare corresponding counterparts. Moreover, such low-temperature in situ growth of graphene demonstrates stable and long-lasting anticorrosion after long-term immersion. This new class of graphene coated nanomaterials shows high potentials in anticorrosion applications for submarines, oil tankers/pipelines, and ruggedized electronics.

Download full-text PDF

Source
http://dx.doi.org/10.1021/acsami.5b09453DOI Listing

Publication Analysis

Top Keywords

low-temperature situ
8
situ growth
8
growth graphene
8
metallic substrates
8
graphene
4
graphene metallic
4
substrates application
4
application anticorrosion
4
anticorrosion metal
4
metal alloy
4

Similar Publications

Effect of cerium-zirconium oxide-loaded red mud on the selective catalytic reduction of NO in downhole diesel vehicle exhaust.

Environ Pollut

January 2025

College of Safety and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, Shandong Province, China; State Key Laboratory of Mining Disaster Prevention and Control Co-found by Shandong Province and the Ministry of Science and Technology, Shandong University of Science and Technology, Qingdao 266590, China.

Red mud (RM), an iron oxide-rich solid waste, shows potential as a catalyst for selective catalytic reduction in denitrification processes. This study investigates the catalytic performance and mechanism of metal-modified RM in reducing NO from diesel vehicle exhaust. Acid-washed RM catalysts were impregnated with varying ratios of cerium (Ce) and zirconium (Zr).

View Article and Find Full Text PDF

The effective elimination of NO from automobile exhaust at low temperatures poses significant challenges. Compared to other materials, supported RhO catalysts exhibit high NO decomposition activities, even in the presence of O, CO, and HO. Metal additives can enhance the low-temperature NO decomposition activities over supported RhO catalysts; however, the enhancement mechanism and active sites require further investigation.

View Article and Find Full Text PDF

Localized Nanoscale Formation of Vanadyl Porphyrin 2D MOF Nanosheets and Their Optimal Coupling to Lumped Element Superconducting Resonators.

J Phys Chem C Nanomater Interfaces

January 2025

Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC - Universidad de Zaragoza, Plaza San Francisco s/n, Zaragoza 50009, Spain.

A strategy toward the realization of a quantum spin processor involves the coupling of spin qubits and qudits to photons within superconducting resonators. To enable the realization of such hybrid architecture, here we first explore the design of a chip with multiple lumped-element LC superconducting resonators optimized for their coupling to distinct transitions of a vanadyl porphyrin electronuclear qudit. The controlled integration of the vanadyl qudit onto the superconducting device, both in terms of number and orientation, is then attained using the formation of nanosheets of a 2D framework built on the vanadyl qudit as a node.

View Article and Find Full Text PDF

An inevitable overoxidation process is considered as one of the most challenging problems in the direct conversion of methane (CH4) to methanol (CH3OH), which is limited by the uncontrollable cracking of key intermediates. Herein, we have successfully constructed a photocatalyst, the Fe-doped ZnO hollow polyhedron (Fe/ZnOHP), for the highly selective photoconversion of CH4 to CH3OH under mild conditions. In-situ experiments and density functional theory calculations confirmed that the introduction of Fe was able to decrease the energy level of the O 2p orbital, which passivated the activity of lattice oxygen in ZnO nanocrystals.

View Article and Find Full Text PDF

Oxygen vacancy and interface effect dual modulation of SnS/SnO heterojunction for boosting formaldehyde detection at low temperature.

Talanta

January 2025

State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, PR China. Electronic address:

Formaldehyde (HCHO) is a harmful volatile organic pollutant, which is commonly found in interior decoration and furniture products. Therefore, it is necessary to develop a gas sensor that can quickly and accurately detect formaldehyde for human health and environmental protection. In order to achieve this goal, in this work, SnS/SnO heterostructure was synthesized by in-situ sulfurization process on the basis of SnO nanospheres, and its formaldehyde sensing performance was studied.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!