The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite. The 1,3-dithiol-2-thione derivative was in turn synthesized by the regioselective bromination of 4-acetyl[2.2]paracyclophane, then through the corresponding dithiocarbamates and 1,3-dithiolium salts.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660956 | PMC |
| http://dx.doi.org/10.3762/bjoc.11.207 | DOI Listing |
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