The contraction of benzene is one of an exclusive group of reactions where the cleavage of aromatic structure is of fundamental importance. Rhodium(III) m-benziporphyrin undergoes an unprecedented transformation of the built-in m-phenylene in which a perimeter carbon atom is extruded to form rhodium(III) 21-carbaporphyrin, stabilizing the formyl-unit-substituted rhodacyclopropane motif.
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| http://dx.doi.org/10.1002/anie.201508033 | DOI Listing |
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