trans-cis Configuration regulated supramolecular polymer gels and chirality transfer based on a bolaamphiphilic histidine and dicarboxylic acids.

Chem Commun (Camb)

Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China. and Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, P. R. China.

Published: January 2016

Supramolecular polymer gels based on the co-assembly of bolaamphiphilic l-histidine(BolaHis) and dicarboxylic acids are dependent on the molar ratios, flexibility and cis-trans configuration of acid molecules. Thus, oligomerized rigid cis-maleic acid or flexible trans-cyclohexane dicarboxylic acid can form chiral supramolecular polymer gels with l-BolaHis.

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Source
http://dx.doi.org/10.1039/c5cc09210hDOI Listing

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