The title complex, [Ag3I2(C25H22P2)3]I·C7H8N2S, comprises a trinuclear [Ag3I2(C25H22P2)3](+) unit, an I(-) anion and one N,N'-phenyl-thio-urea mol-ecule (ptu). Two μ3-bridging I(-) anions are linked by three Ag(I) ions, leading to the formation of a dicapped triangular motif with Ag⋯Ag separations in the range 3.0823 (5)-3.2999 (5) Å. Each Ag(I) atom exhibits a distorted tetra-hedral geometry, with coordination to two I atoms and two P atoms from bis-(di-phenyl-phosphan-yl)methane ligands. In the crystal, the I(-) anion is linked to the ptu mol-ecule through two N-H⋯I hydrogen bonds [graph-set motif R 2 (1)(6)]. These N-H⋯I hydrogen bonds, in addition to weak C-H⋯S and C-H⋯I hydrogen bonds, form zigzag chains along [010]. Two of the phenyl rings of two dppm ligands are disordered over two sets of sites with refined occupancies of 0.557 (16) and 0.443 (16).
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645055 | PMC |
| http://dx.doi.org/10.1107/S2056989015017120 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Single-Site Local-Density Potentials for the Mesoscopic Representation of Water Based on the SAFT-VR Mie Equation of State.
J Phys Chem B
January 2025
Department of Chemical Engineering, School of Engineering, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
In this article, we present three mesoscopic models for water. All three models make use of local density-dependent interaction potentials, as employed within the Pagonabarraga-Frenkel framework [Pagonabarraga, I.; Frenkel, D.
View Article and Find Full Text PDFDetermination of the degree of sulfonation in cross-linked and non-cross-linked Poly(ether ether ketone) using different analytical techniques.
Heliyon
January 2025
Division of Polymer Chemistry, Department of Chemistry, Atomic Energy Commission, P.O. Box: 6091, Damascus, Syrian Arab Republic.
The degree of sulfonation (DS) is a key property of sulfonated polymers, as it significantly influences their swelling behaviour, conductivity and mechanical properties. Accurately determining the DS is essential for optimizing these materials for various applications. In this work, the DS of sulfonated poly (ether ether ketone) (SPEEK) was evaluated using a combination of analytical techniques, including titration, back titration, Fourier Transform Infrared (FTIR), Ultra-Violet (UV) and proton nuclear magnetic resonance (H NMR) spectroscopies, Thermogravimetric analysis (TGA), Rutherford backscattering (RBS) and particle induced X-ray emission (PIXE) analysis.
View Article and Find Full Text PDFA scalable and eco-friendly carbohydrate-based oleogelator for vitamin E controlled delivery.
RSC Adv
January 2025
Univ. Grenoble Alpes, CNRS, CERMAV 38000 Grenoble France
Supramolecular oleogels, in which low-molecular weight oleogelators self-assemble into various nanostructures through non-covalent interactions, have witnessed increasing research activity in various fields of science, including food, cosmetics or remediation of marine oil spills. Herein, we report a simple scalable and environmentally friendly carbohydrate-based oleogelator, namely, the sodium salt of ,'-dimethyl β- glucosyl barbiturate (GlcBMe) that self-assembles through sonication to induce the gelation of polar organic solvent and later of non-polar vegetable oils by cationic exchange with quaternary ammonium surfactants. Water-soluble GlcBMe was capable of forming self-assembled fibrillar network bridging insoluble particles in the oil by sonication in the presence of a small amount of water.
View Article and Find Full Text PDFA novel imatinib analogue inhibitor of chronic myeloid leukaemia: design, synthesis and characterization-explanation of its folded conformation.
R Soc Open Sci
January 2025
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, UK.
Chronic myeloid leukaemia (CML) is primarily treated using imatinib mesylate, a tyrosine kinase inhibitor (TKI) targeting the BCR::ABL1 oncoprotein. However, the development of drug resistance and adverse side effects necessitate the exploration of alternative therapeutic agents. This study presents the synthesis and characterization of a novel imatinib analogue, 3-chloro--(2-methyl-5-((4-(pyridin-2-yl)pyrimidin-2-yl)amino)phenyl)benzamide (PAPP1).
View Article and Find Full Text PDFSodium butyrate regulates macrophage polarization by TGR5/β-arrestin2 in vitro.
Mol Med
January 2025
Department of Critical Care Medicine, Renmin Hospital of Wuhan University, 238 Jiefang Road, Wuchang, Wuhan, 430060, Hubei, China.
Background: Macrophages play an important role in the pathogenesis of ulcerative colitis (UC). We will explore the effects of sodium butyrate (SB) on macrophage function.
Methods: The targets of butyric acid were identified using SwissTargetPrediction database and surface plasmon resonance (SPR).
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!