Crystal structure of 3a,6,6,9a-tetra-methyl-dodeca-hydro-naphtho-[2,1-b]furan-2-ol.

Acta Crystallogr E Crystallogr Commun

Xi'an Botanical Garden, Institute of Botany of Shaanxi Province, Xi'an 710061, People's Republic of China.

Published: October 2015

The title compound (common name: sclaral), C16H28O2, is a sclareolide derivative, which was synthesized from sclareolide itself. In the mol-ecule, the two six-membered rings, A and B, of the labdane skeleton adopt chair conformations and the five-membered O-containing heterocyclic ring C displays an envelope conformation, with the methine C atom of the fused C-C bond as the flap. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, forming chains propagating along [100].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647384PMC
http://dx.doi.org/10.1107/S2056989015016370DOI Listing

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