Nine members of a family of nine-membered cyclic coordination clusters; Fe6Ln3 wheels (Ln = Gd to Lu and Y).

Chem Commun (Camb)

Institut für Anorganische Chemie, KIT (Karlsruhe Institute of Technology), Engesserstr. 15, 76131 Karlsruhe, Germany. and Institut für Nanotechnologie, KIT (Karlsruhe Institute of Technology), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany.

Published: January 2016

We report a family of isostructural nonanuclear Fe(III)-Ln(III) cyclic coordination clusters [Fe(III)(6)Ln(III)(3)(μ-OMe)9(vanox)6(benz)6]. (Ln = Tb (1), Dy (2), Ho (3), Er (4), Tm (5), Yb (6), Lu (7), Y (8) and Gd (9)), containing an odd number of metal ions. The planar cyclic coordination cluster cores are built up from three [Fe2Ln] subunits.

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Source
http://dx.doi.org/10.1039/c5cc08887aDOI Listing

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