Ce doped ZnTiO3 as a novel catalyst with highly efficient and stable sonocatalytic activity was synthesized via an ultrasound-assisted sol-gel method using non-ionic surfactant Pluronic F127 as structure directing agent. Synthesized samples were characterized by using various techniques, such as XRD, TEM, SEM, EDX, XRF, BET, DRS, and PL, and their sonocatalytic activity studied toward degradation of p-Nitrophenol as a model organic compound. The synthesized mesoporous Ce/ZnTiO3 had mixed cubic-hexagonal phase with large surface area (118.2 m(2) g(-1)) and narrow pore size distribution (4.9 nm). The effects of cerium concentration, calcination temperature, and calcination time on the structure and the sonocatalytic activity of Ce/ZnTiO3 were studied in detail. XRD results were suggested that the relation between the phase structure and the catalytic activity is considerable. Significant decrease in band-gap and PL intensity was observed with increasing the cerium concentration in the ZnTiO3. It became clear that the Ce/ZnTiO3 (0.81 mol%) shows high sonocatalytic activity compared with pure ZnTiO3 and other Ce/ZnTiO3 samples as well as commercial TiO2-P25. The possible mechanism for the enhanced sonocatalytic activity of Ce/ZnTiO3 was discussed in details. The electrical energy consumption was also considered during sonocatalytic experiments.
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http://dx.doi.org/10.1016/j.ultsonch.2015.10.004 | DOI Listing |
Nanomaterials (Basel)
November 2024
College of Civil Engineering, Sichuan Agricultural University, Dujiangyan 611830, China.
J Colloid Interface Sci
March 2025
School of Materials and Chemistry, Institute of Bismuth Science, University of Shanghai for Science and Technology, Shanghai 200093, China; Shanghai Collaborative Innovation Center of Energy Therapy for Tumors, Shanghai 200093, China. Electronic address:
Artificially synthesized nanozymes exhibit enzymatic activity similar to that of natural enzymes. However, in the complex tumor microenvironment, their diversity and catalytic activity show significant variations, limiting their effectiveness in catalytic therapy. Developing artificial enzymes with multiple enzymatic activities and spatiotemporal controllable catalytic abilities is of great clinical significance.
View Article and Find Full Text PDFMolecules
November 2024
College of Chemistry, Chemical Engineering, and Materials Science, Soochow University, Suzhou 215123, China.
Cu(II) and Mn(II) coordination polymers [Cu(ttpa)(sub)] ( or ) and {[Mn(ttpa)(nip)(HO)]·3HO} ( or ) (ttpa = tris(4-(1,2,4-triazol-1-yl)phenyl)amine, Hsub = suberic acid, nip = 5-nitroisophthalicate) were hydrothermally prepared and the structures were characterized. exhibited a 2D (4,4) network based on [Cu(COO)] dimers with upper and lower dangled ttpa ligands and a 2D → 3D polythreaded network. showed a 2D (4,4) network with dangled uncoordinated triazole rings from ttpa ligands and nitro groups from nip ligands and a 2D → 3D polythreaded network.
View Article and Find Full Text PDFBiomaterials
April 2025
Department of Anesthesiology, Shanghai Chest Hospital, Shanghai Jiao Tong University, School of Medicine, Shanghai, 200030, China. Electronic address:
Inducing reactive oxygen species (ROS) via sonocatalysis to initiate inflammatory programmed cell death (PANoptosis) and immunogenic cell death (ICD) presents a promising strategy for activatable cancer immunotherapy. However, the limited ROS generation by sonosensitizers under ultrasound and the immunosuppressive tumor microenvironment hinder the efficiency of sono-immunotherapy. To overcome these challenges, a bismuth-based ternary heterojunction, Bi@BiO-Pt-PEG (BBOP), was developed for sonocatalytic therapy aimed at activating immune responses.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Department of Medical Ultrasound, Center of Minimally Invasive Treatment for Tumor, Shanghai Tenth People's Hospital, School of Medicine, Tongji University, Shanghai, 200072, P. R. China.
Pyroptosis, an inflammatory cell death, has attracted great attention for potentiating a strong immune response against tumor cells. However, developing powerful pyroptosis inducers and then activating specific pyroptosis still remains challenging. Herein, a PEG-CuP-COF@∆St nanosystem is rationally designed, consisting of PEG-CuP-COF nanozyme pyroptosis inducers and tumor-targeting bacteria of the Salmonella Typhimurium strain VNP20009 (ΔSt), with an affinity for the tumor hypoxic microenvironment.
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