In this work, we report on indium tin oxide-free, all-solution processed transparent organic light emitting diodes (OLEDs) with inverted device architecture. Conductive polymer layers are employed as both transparent cathodes and transparent anodes, with the top anodes having enhanced conductivities from a supporting stochastic silver nanowire mesh. Both electrodes exhibit transmittances of 80-90% in the visible spectral regime. Upon the incorporation of either yellow- or blue-light emitting fluorescent polymers, the OLEDs show low onset voltages, demonstrating excellent charge carrier injection from the polymer electrodes into the emission layers. Overall luminances and current efficiencies equal the performance of opaque reference OLEDs with indium tin oxide and aluminium electrodes, proving excellent charge carrier-to-light conversion within the device.
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http://dx.doi.org/10.1039/c5nr05820a | DOI Listing |
Polymers (Basel)
October 2024
Department of Materials Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan.
In recent years, third-generation solar cells have experienced a remarkable growth in efficiency, making them a highly promising alternative energy solution. Currently, high-efficiency solar cells often use top electrodes fabricated by thermal evaporation, which rely on high-cost and high energy-consumption vacuum equipment, raising significant concerns for mass production. This study develops a method for fabricating silver electrodes using the screen-printing process, aiming to achieve solar cell production through an all-solution coating process.
View Article and Find Full Text PDFNano Lett
October 2024
School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, Guangdong 518172, P. R. China.
Silicon heterojunction (SHJ) solar cells have set world-record efficiencies among single-junction silicon solar cells, accelerating their commercial deployment. Despite these clear efficiency advantages, the high costs associated with low-temperature silver pastes (LTSP) for metallization have driven the search for more economical alternatives in mass production. 2D transition metal carbides (MXenes) have attracted significant attention due to their tunable optoelectronic properties and metal-like conductivity, the highest among all solution-processed 2D materials.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2024
Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
AgNW networks show high promise as a conductive material due to excellent flexibility, low resistance, high transparency, and ease of large-scale preparation. However, the application of AgNW networks has been hindered by their inherent characteristics, such as easy oxidation degradation, chemical corrosion, and structural instability at high temperatures. In this study, a dense SiO protective layer derived from perhydropolysilazane was introduced to fabricate a robust SiO/AgNW nanocomposite coating through an all-solution process at room temperature.
View Article and Find Full Text PDFNat Commun
July 2024
Department of Chemistry, Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Tsinghua University, Beijing, 100084, China.
Solution-processable 2D semiconductor inks based on electrochemical molecular intercalation and exfoliation of bulk layered crystals using organic cations has offered an alternative pathway to low-cost fabrication of large-area flexible and wearable electronic devices. However, the growth of large-piece bulk crystals as starting material relies on costly and prolonged high-temperature process, representing a critical roadblock towards practical and large-scale applications. Here we report a general liquid-metal-assisted approach that enables the electrochemical molecular intercalation of low-cost and readily available crystal powders.
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