Self-assembly of block copolymers on lithographically patterned template with ordered posts.

Phys Chem Chem Phys

Institute of Theoretical Chemistry, Jilin University, Changchun 130021, China.

Published: December 2015

AI Article Synopsis

  • Dissipative particle dynamics simulations were used to investigate how block copolymers self-assemble on templates with hexagonally and rectangularly arranged posts.
  • The study found that the arrangement of the posts significantly affects the resulting polymer morphologies, with hexagonal templates leading to bending alignments.
  • By adjusting the spacing between posts in rectangular templates, different mesh-shaped structures can be created, offering insights for designing materials on a nanometer scale through directed self-assembly techniques.

Article Abstract

Dissipative particle dynamics simulations are employed to study the self-assembly of block copolymers on a template modified with ordered posts. Templates with hexagonally arranged and rectangularly arranged posts are both studied. For the systems with hexagonally arranged posts, morphologies with bending alignments are seen most often. We find that the different kinds of patterns, which can be directly observed in experiments, are substantially induced by the pattern of the bottom layer. In the simulations with a template modified with rectangularly arranged posts, by finely adjusting the distances between neighboring posts in both x and y directions, mesh-shaped structures with different angles between the bottom and the sub-bottom layers can be obtained. These results shed light on the better design of lithographically patterned materials on the scale of 10 nm via the directed self-assembly of BCPs by templating.

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Source
http://dx.doi.org/10.1039/c5cp05449dDOI Listing

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