This review recapitulates all available literature dealing with the synthesis and reactivity of geminal organic di- and triazides. These compound classes are, to a large extent, unexplored despite their promising chemical properties and their simple preparation. In addition, the chemistry of carbonyl diazide (2) and tetraazidomethane (105) is described in separate sections.
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Division of Materials Science, Graduate School of Science and Technology , Nara Institute of Science and Technology (NAIST), 8916-5 Takayamacho , Ikoma , Nara 630-0192 , Japan.
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