Use of ferroelectric domain-walls in future electronics requires that they are stable, rewritable conducting channels. Here we demonstrate nonthermally activated metallic-like conduction in nominally uncharged, bent, rewritable ferroelectric-ferroelastic domain-walls of the ubiquitous ferroelectric Pb(Zr,Ti)O3 using scanning force microscopy down to a temperature of 4 K. New walls created at 4 K by pressure exhibit similar robust and intrinsic conductivity. Atomic resolution electron energy-loss spectroscopy confirms the conductivity confinement at the wall. This work provides a new concept in "domain-wall nanoelectronics".
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http://dx.doi.org/10.1021/acs.nanolett.5b03450 | DOI Listing |
Phys Rev E
September 2024
Department of Physics, Federal Rural University of Pernambuco, Recife 52171-900, Brazil.
The synthesis of ferroelectric nematic liquid crystals (FNLCs) concludes the long wait for their existence and potential usage in multiple liquid crystal based applications. In FNLCs, electric polarization in the nematic phase significantly decreases the switching time of in-on display pixels. In this article, we report the occurrence of translation symmetry breaking for heat propagation along the director field n[over ̂] in the ferroelectric nematic phase.
View Article and Find Full Text PDFSoft Matter
September 2024
Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector 81, Knowledge City, Manauli 140306, India.
Non-symmetrical cholesterol-based dimers have emerged as crucial materials in the field of liquid crystal research, owing to their remarkable ability to stabilize various exotic mesophases, including the blue phases (BPIII, BPII, BPI), cholesteric nematic (N*) phase, smectic blue phase (SmBP), twist grain boundary (TGB) phase, smectic A/smectic A* (SmA/SmA*) phase, and smectic C/smectic C* (SmC/SmC*) phase. These mesophases have garnered considerable attention due to their diverse applications in spatial light modulation, chiro-optical devices, optical switching, thermochromic materials, and more. In this study, we present the synthesis and comprehensive characterization of a series of non-symmetrical cholesterol-based bent-shaped dimers (1/12, 1/14, 1/16) in which the cholesterol unit is intricately linked to an aromatic mesogenic core through a flexible spacer.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2023
Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States.
Resistive random-access memory (RRAM) is a promising technology for data storage and neuromorphic computing; however, cycle-to-cycle and device-to-device variability limits its widespread adoption and high-volume manufacturability. Improving the structural accuracy of RRAM devices during fabrication can reduce these variabilities by minimizing the filamentary randomness within a device. Here, we studied area-selective atomic layer deposition (AS-ALD) of the HfO dielectric for the fabrication of RRAM devices with higher reliability and accuracy.
View Article and Find Full Text PDFJ Phys Chem B
July 2023
Institute of Innovative Research, Tokyo Institute of Technology, 4259, Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8503, Japan.
A dimeric molecule, di-5(3FM-C4T), with fluoro-substituted mesogenic cores composed of three-aromatic rings and linked by a pentamethylene spacer is prepared. Di-5(3FM-C4T) forms the ferroelectric nematic (N), ferroelectric smectic-A (SmAP), and polar isotropic (Iso) phases. The N phase is composed of molecules in U-shaped conformation that behave like polar rod-like molecules.
View Article and Find Full Text PDFACS Nano
April 2023
Department of Materials Science and Engineering, University of Illinois Urbana-Champaign, Urbana, Illinois 61801, United States.
The low bending stiffness of atomic membranes from van der Waals ferroelectrics such as α-InSe allow access to a regime of strong coupling between electrical polarization and mechanical deformation at extremely high strain gradients and nanoscale curvatures. Here, we investigate the atomic structure and polarization at bends in multilayer α-InSe at high curvatures down to 0.3 nm utilizing atomic-resolution scanning transmission electron microscopy, density functional theory, and piezoelectric force microscopy.
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