We fabricate and characterize large-area plasmonic substrates that feature asymmetric periodic nanostructures made of aluminum. Strong coupling between localized and propagating plasmon resonances leads to characteristic Fano line shapes with tunable spectral positions and widths. Distinctive colors spanning the entire visible spectrum are generated by tuning the system parameters, such as the period and the length of the aluminum structures. Moreover, the asymmetry of the aluminum structures gives rise to a strong symmetry broken color rendering effect, for which colors are observed only from one side of the surface normal. Using a combination of immersed laser interference lithography and nanoimprint lithography, our color rendering structures can be fabricated on areas many inches in size. We foresee applications in anticounterfeiting, photovoltaics, sensing, displays, and optical security.
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http://dx.doi.org/10.1021/acsnano.5b05710 | DOI Listing |
Nat Commun
January 2025
The Organic Photonics and Electronics Group, Department of Physics, Umeå University, Umeå, Sweden.
The attainment of white emission from a light-emitting electrochemical cell (LEC) is important, since it enables illumination and facile color conversion from devices that can be cost-efficient and sustainable. However, a drawback with current white LECs is that they either employ non-sustainable metals as an emitter constituent or are intrinsically efficiency limited by that the emitter only converts singlet excitons to photons. Organic compounds that emit by thermally activated delayed fluorescence (TADF) can address these issues since they can harvest all excitons for light emission while being metal free.
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Chemistry, Beijing Technology and Business University, Beijing 100048, China.
Isostructured lanthanide-Brønsted acidic ionic liquid coordination polymers, {[Ln(CHNO)(HO)]Cl} (LnIMDC(HO), Ln = Eu, Gd, or Tb, CHNO = [IMDC]) and {[EuTb(CHNO)(HO)]Cl} (EuTbIMDC(HO))), have been synthesized using 1,3-bis(carboxymethyl) imidazolium chloride ([HIMDC]Cl) as linkers. LnIMDC(HO) (Ln = Eu or Tb) and EuTbIMDC(HO) exhibit good temperature sensing performance over a wide temperature range with maximum sensitivities of 2.73%·K (392 K) and 2.
View Article and Find Full Text PDFInorg Chem
January 2025
Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, Shaanxi, P. R. China.
Many phosphor hosts, for example, nitrides and sulfides, often face challenges such as hydrolysis and oxidation, limiting their application in phosphor-converted white light-emitting diodes (pc-LEDs). In this study, we developed a highly humidity-resistant yellow-green-emitting phosphor BaSiNO:Ce (BSNO:Ce). The DFT calculations revealed a high Debye temperature (Θ = 1159 K), indicating a rigid crystal structure that contributes to the photoluminescence thermal quenching resistance of BSNO.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
The Liaoning Province Key Laboratory of Paper and Pulp Engineering, The Dalian Key Laboratory of High value application and development of Botanical Resources, The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China; Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, School of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China. Electronic address:
As a novel fluorescent carbon nanomaterial, carbon dots are restricted by their poor fluorescence in the solid state, although they exhibit favorable photoluminescence in solution. N-doped carbon dots (N-CDs) and solid-state fluorescence films were prepared using green and renewable cellulose-derived materials, respectively. The hydrogen bonding network of carboxymethyl cellulose (CMC) inhibits the self-aggregation behavior of N-CDs, which leads to solid-state fluorescence.
View Article and Find Full Text PDFLangmuir
January 2025
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.
The lateral flow assay is a strip-based analytical method for the portable and convenient detection of analytes of interest. It has the advantages of visual observation, autonomous sample flow, fast coloration time, minimal tedious operation procedures, and reliance on specialized instruments. However, the rough surface of the nitrocellulose membrane renders it difficult for the immobilized nucleic acids to remain in an ordered arrangement, and the immobilized nucleic acids are also liable to be digested in a complex matrix, inducing limited sensitivity and anti-interference.
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