Adiabatic demagnetization is currently gaining strong interest in searching for alternatives to (3)He-based refrigeration techniques for achieving temperatures below 2 K. The main reasons for that are the recent shortage and high price of the rare helium isotope (3)He. Here we report the discovery of a large magnetocaloric effect in the intermetallic compound YbPt2Sn, which allows adiabatic demagnetization cooling from 2 K down to 0.2 K. We demonstrate this with a home-made refrigerator. Other materials, for example, paramagnetic salts, are commonly used for the same purpose but none of them is metallic, a severe limitation for low-temperature applications. YbPt2Sn is a good metal with an extremely rare weak magnetic coupling between the Yb atoms, which prevents them from ordering above 0.25 K, leaving enough entropy free for use in adiabatic demagnetization cooling. The large volumetric entropy capacity of YbPt2Sn guarantees also a good cooling power.
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http://dx.doi.org/10.1038/ncomms9680 | DOI Listing |
J Am Chem Soc
January 2025
Department of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.
Attaining sub-Kelvin temperatures remains technologically challenging and often relies on the scarce resource He, unless employing adiabatic demagnetization refrigeration. Herein, the active coolant typically consists of weakly coupled paramagnetic ions, whose magnetic interaction strengths are comparable in energy to the relevant temperature regime of cooling. Such interactions depend strongly on inter-ion distances, fundamentally hindering the realization of dense coolants for sub-Kelvin refrigeration.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, People's Republic of China.
Adiabatic demagnetization refrigeration (ADR) based on the magnetocaloric effect (MCE) is a promising technique to achieve cryogenic temperature. However, magnetic entropy change (Δ), the driving force of ADR, remains far below theoretical -Δ = ln(2 + 1)/ for most magnetic refrigerants. Here, we report giant MCE in orthorhombic EuCl, where a ferromagnetic ground state with excellent single-ion behavior of Eu and free spins has been demonstrated by combining calculations with Brillouin function analysis and magnetic measurements.
View Article and Find Full Text PDFChem Commun (Camb)
November 2024
Chemistry Program, Louisiana Tech University, Ruston, Louisiana 71272, USA.
Herein, we report an improvement over Hartmann-Hahn cross polarization for NMR signal enhancement: adiabatic demagnetization/remagnetization transfers that provide up to a 9-fold experimental speedup for C NMR signals in amino acids over conventional means. The experiment proved insensitive to site type, and we also demonstrate a means for making it compatible with high-resolution spectroscopy.
View Article and Find Full Text PDFJ Phys Condens Matter
October 2024
Experimental Physics VI, Center for Electronic Correlations and Magnetism, Institute of Physics, University of Augsburg, 86159 Augsburg, Germany.
The manifold of energetically degenerate configurations arising from competing interactions in frustrated magnets gives rise to an enhanced entropy at lowest temperatures, which can be utilized for adiabatic demagnetization refrigeration (ADR). We review structural and magnetic properties of various Yb- and Gd-based oxides featuring frustration related to different triangular moment configurations and (in some cases) structural randomness. In comparison to paramagnetic hydrated salts, which have traditionally been employed for mK-ADR, these novel ADR materials enable cooling to temperatures several times lower than the magnetic interaction strength, significantly enhancing the entropy density and cooling power at a given target temperature.
View Article and Find Full Text PDFJ Am Chem Soc
July 2024
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China.
Adiabatic demagnetization refrigeration (ADR) is a promising cooling technology with high efficiency and exceptional stability in achieving ultralow temperatures, playing an indispensable role at the forefront of fundamental and applied science. However, a significant challenge for ADR is that existing magnetic refrigerants struggle to concurrently achieve low magnetic ordering temperatures () and substantial magnetic entropy changes (-Δ) at ultralow temperatures. In this work, we propose the combination of Gd and Yb to effectively regulate both -Δ and in ultralow temperatures.
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