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The tetrathiafulvalene-scaffold (TTF) reacts selectively in allylation, acylation, arylation, halogenation, and thiolation reactions via magnesium or zinc derivatives that are obtained by a direct metalation with Mg- and Zn-TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl). This stepwise functionalization provides access to a range of new mono-, di-, tri-, and tetra-functionalized TTF-derivatives and allows for fine-tuning of their energy levels.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797621 | PMC |
| http://dx.doi.org/10.1021/acs.orglett.5b02715 | DOI Listing |
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