Using an optimized lift-off process we develop a technique for both nanoscale and single-dot patterning of colloidal quantum dot films, demonstrating feature sizes down to ~30 nm for uniform films and a yield of 40% for single-dot positioning, which is in good agreement with a newly developed theoretical model. While first of all presenting a unique tool for studying physics of single quantum dots, the process also provides a pathway toward practical quantum dot-based optoelectronic devices.
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http://dx.doi.org/10.1021/acs.nanolett.5b03068 | DOI Listing |
Nanoscale
October 2024
School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute (HBNI), Khurda, Odisha 752050, India.
Nanoscale
August 2024
Department of Chemistry, McGill University, Montreal, H3A 0B8, Canada.
Metal halide semicondictor perovskites have been under intense investigation for their promise in light absorptive applications like photovoltaics. They have more recently experienced interest for their promise in light emissive applications. A key aspect of perovskites is their glassy, ionic lattice that exhibits dynamical disorder.
View Article and Find Full Text PDFFeatured with its extraordinary super-resolution capability, the advent of stimulated emission depletion (STED) lithography has allowed for vastly reduced minimum feature size of a single pixel down to the deep sub-diffraction scale so as to produce unprecedented nanofeatures. However, the anticipated sub-diffraction pixel pitch down below 100 nm remains out of reach due to redundant polymerization of adjacent exposures at a short distance, so called memory effect. In this work, a nanoprinting-at-expansion/employments-at-recovery strategy is applied in the dual-beam STED lithography technique to surmount the memory effect and break adjacent-exposure limit imposed on minimizing the pixel pitch.
View Article and Find Full Text PDFNanoscale
January 2023
The Blackett Laboratory, Department of Physics, Imperial College London, London SW7 2BW, UK.
Giant shell CdSe/CdS quantum dots are bright and flexible emitters, with near-unity quantum yield and suppressed blinking, but their single photon purity is reduced by efficient multiexcitonic emission. We report the observation, at the single dot level, of a large blueshift of the photoluminescence biexciton spectrum (24 ± 5 nm over a sample of 32 dots) for pure-phase wurtzite quantum dots. By spectral filtering, we demonstrate a 2.
View Article and Find Full Text PDFSensors (Basel)
March 2022
Panevezys Faculty of Technology and Business, Kaunas University of Technology, 44249 Kaunas, Lithuania.
The trade-off between the functionalization shift of the informative parameters and sensitivity of capacitive micromachined ultrasound transducers (CMUT)-based CO sensors is addressed, and the CMUT surface modification process by thin inkjet-printed polyethyleneimine (PEI) films is optimized. It was shown that by the proper preparation of the active CMUT surface and properly diluted PEI solution, it is possible to minimize the functionalization shift of the resonance frequency and the quality of the resonance and preserve the sensitivity potential. So, after optimization, we demonstrated 23.
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