Contact probe voltammetry for in situ monitoring of the reactivity of phenolic tomato (Solanum lycopersicum L.) compounds with ROS.

Talanta

Packaging Lab., Instituto de Agroquímica y Tecnología de Alimentos, IATA-CSIC, Av. Agustín Escardino 7, 46980 Paterna, Valencia, Spain. Electronic address:

Published: November 2015

The application of an in situ electrochemical contact probe methodology for monitoring reactivity of antioxidant polyphenolic compounds in tomato fruits is described. Upon electrochemical generation of reactive oxygen species (ROS), characteristic voltammetric responses were recorded for compounds resulting from the reaction of such species with tomato compounds. This suggests that new electrochemically oxidizable compounds are generated from the oxidation of highly reactive polyphenolic compounds with ROS. Therefore, an evaluation of the antioxidant capacity of such species could be made from voltammetric data for different tomato varieties.

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http://dx.doi.org/10.1016/j.talanta.2015.07.092DOI Listing

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