This paper illustrates the effect of substrate topography on morphology evolution in nanoporous gold (np-Au) thin films. One micron-high silicon ridges with widths varying between 150 nm to 50 µm were fabricated and coated with 500 nm-thick np-Au films obtained by dealloying sputtered gold-silver alloy films. Analysis of scanning electron micrographs of the np-Au films following dealloying and thermal annealing revealed two distinct regimes where the ratio of film thickness to ridge width determines the morphological evolution of np-Au films.
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http://dx.doi.org/10.1016/j.scriptamat.2015.07.039 | DOI Listing |
Nanomaterials (Basel)
April 2024
Department of Electrical and Computer Engineering, University of California-Davis, Davis, CA 95616, USA.
Nanoporous gold (np-Au) has found its use in applications ranging from catalysis to biosensing, where pore morphology plays a critical role in performance. While the morphology evolution of bulk np-Au has been widely studied, knowledge about its thin-film form is limited. This work hypothesizes that the mechanical compliance of the thin film substrate can play a critical role in the morphology evolution.
View Article and Find Full Text PDFNanomaterials (Basel)
May 2023
Graduate Institute of Photonics and Optoelectronics and Department of Electrical Engineering, National Taiwan University, Taipei 10617, Taiwan.
Amorphous-Ge (α-Ge) or free-standing nanoparticles (NPs) synthesized via hydrogen-free plasma-enhanced chemical vapor deposition (PECVD) were applied as transmissive or reflective saturable absorbers, respectively, for starting up passively mode-locked erbium-doped fiber lasers (EDFLs). Under a threshold pumping power of 41 mW for mode-locking the EDFL, the transmissive α-Ge film could serve as a saturable absorber with a modulation depth of 52-58%, self-starting EDFL pulsation with a pulsewidth of approximately 700 fs. Under a high power of 155 mW, the pulsewidth of the EDFL mode-locked by the 15 s-grown α-Ge was suppressed to 290 fs, with a corresponding spectral linewidth of 8.
View Article and Find Full Text PDFNanomaterials (Basel)
February 2021
Department of Electrical and Computer Engineering, University of California, Davis, CA 95616, USA.
Sustained release and replenishment of the drug depot are essential for the long-term functionality of implantable drug-delivery devices. This study demonstrates the use nanoporous gold (np-Au) thin films for in-plane transport of fluorescein (a small-molecule drug surrogate) over large (mm-scale) distances from a distal reservoir to the site of delivery, thereby establishing a constant flux of molecular release. In the absence of halides, the fluorescein transport is negligible due to a strong non-specific interaction of fluorescein with the pore walls.
View Article and Find Full Text PDFNanomaterials (Basel)
June 2018
Department of Electrical and Computer Engineering, University of California-Davis, Davis, CA 95616, USA.
Nanoporous gold (np-Au) electrode coatings have shown improved neural electrophysiological recording fidelity in vitro, in part due to reduced surface coverage by astrocytes. This reduction in astrocytic spreading has been attributed to the influence of electrode nanostructure on focal adhesion (FA) formation. This study describes the development and use of a microfluidic flow cell for imposing controllable hydrodynamic shear on astrocytes cultured on gold surfaces of different morphologies, in order to study the influence of nanostructure on astrocyte adhesion strength as a function of np-Au electrode morphology.
View Article and Find Full Text PDFLangmuir
February 2018
Department of Mechanical and Aerospace Engineering and ‡Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22903, United States.
Drug delivery devices are generally inefficient when releasing the active compound at the targeted position. In this work, we investigate nanoporous gold (np-Au) as the drug eluting device, and we use the precipitation of NaCl as a model of drug sedimentation to evaluate the patterns of solute distribution. Hydrophilic and hydrophobic modifications of np-Au result in different, but both inhomogeneous, release patterns, with most of the precipitate forming outside the device.
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