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Synthesis of glycosyl fluorides from (phenylthio)glycosides using IF5-pyridine-HF. | LitMetric

Synthesis of glycosyl fluorides from (phenylthio)glycosides using IF5-pyridine-HF.

Carbohydr Res

Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan. Electronic address:

Published: November 2015

IF5-pyridine-HF, an air- and moisture-stable fluorinating reagent, was applied to the synthesis of glycosyl fluorides from (phenylthio)glycosides. Common protecting groups of alcohol and diol can tolerate the reaction conditions performed, and therefore, the present method is applicable to the synthesis of various glycosyl fluorides.

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Source
http://dx.doi.org/10.1016/j.carres.2015.08.005DOI Listing

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