The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords "1(st) generation" cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578444 | PMC |
| http://dx.doi.org/10.3762/bjoc.11.166 | DOI Listing |
Publication Analysis
Top Keywords
"1st generation"
8
olefin metathesis
8
triisopropyl phosphite
8
ruthenium indenylidene
4
indenylidene "1st
4
generation" olefin
4
metathesis catalysts
4
catalysts triisopropyl
4
phosphite reaction
4
reaction triisopropyl
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!