Nano sized indium oxide is found to be an efficient catalyst for the conversion of thiols to sulfides using Na2CO3 as base and TBATB as reagent in DMSO at 110 °C. Here in situ generation of bromo intermediate by TBATB takes place through indium surface. A variety of aryl sulfides can be synthesized in excellent yields from less reactive chlorides, boronic acids and thiols.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4586445 | PMC |
| http://dx.doi.org/10.1038/srep13873 | DOI Listing |
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