An ultrathin (few nanometer) polymer spacer layer is softened by local optical heating and restructured by strong capillary forces, which increase the gap between the plasmonic metal components. This results in a continuous blue-shift of the coupled plasmon from near infrared to visible with a tuning range of >150 nm that can be tightly controlled by adjusting either irradiation time or power.
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http://dx.doi.org/10.1002/adma.201503292 | DOI Listing |
Nanoscale
February 2024
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication and CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, 100190, China.
The mechanical behaviors of 2D materials are fundamentally important for their potential applications in various fields. α-Molybdenum trioxide (α-MoO) crystals with unique electronic, optical, and electrochemical properties, have attracted extensive attention for their use in optoelectronic and energy conversion devices. From a mechanical viewpoint, however, there is limited information available on the mechanical properties of α-MoO.
View Article and Find Full Text PDFACS Omega
November 2022
Institute of Chemical Physics, University of Latvia, 19 Raina Blvd., Riga LV-1586, Latvia.
A new composite metal-insulator-metal (MIM) system consisting of exceptionally dense non-close-packed (NCP) arrays of gold or silver nanoparticles, porous anodic aluminum oxide (PAAO), and bulk aluminum substrate interacts strongly with visible light and may become a very useful component for optical applications. The proposed MIM structure can be synthesized using accessible lithography-free chemical and physical processes (anodization and capillary force assisted colloidal particle deposition) that are suitable for the low-cost production of specialized devices. Here, we present a systematic study to determine the essential MIM structure parameters (nanoparticle size and PAAO layer thickness) for localized surface plasmon resonance (LSPR) refractometric sensing.
View Article and Find Full Text PDFCarbohydr Polym
March 2022
Department of Fiber and Polymer Technology, Wallenberg Wood Science Center, KTH Royal Institute of Technology, 10044 Stockholm, Sweden. Electronic address:
Nanocomposites based on components from nature, which can be recycled are of great interest in new materials for sustainable development. The range of properties of nacre-inspired hybrids of 1D cellulose and 2D clay platelets are investigated in nanocomposites with improved nanoparticle dispersion in the starting hydrocolloid mixture. Films with a wide range of compositions are prepared by capillary force assisted physical assembly (vacuum-assisted filtration) of TEMPO-oxidized cellulose nanofibers (TOCN) reinforced by exfoliated nanoclays of three different aspect ratios: saponite, montmorillonite and mica.
View Article and Find Full Text PDFNanomaterials (Basel)
April 2019
Institute of Chemical Physics, University of Latvia, 19 Raina Blvd., LV-1586 Riga, Latvia.
This study demonstrates a new, robust, and accessible deposition technique of metal nanoparticle arrays (NPAs), which uses nanoporous anodic alumina (NAA) as a template for capillary force-assisted convective colloid (40, 60, and 80 nm diameter Au) assembly. The NPA density and nanoparticle size can be independently tuned by the anodization conditions and colloid synthesis protocols. This enables production of non-touching variable-density NPAs with controllable gaps in the 20-60 nm range.
View Article and Find Full Text PDFAdv Mater
November 2015
Nanophotonics Centre, Cavendish Laboratory, University of Cambridge, Cambridge, CB3 0HE, UK.
An ultrathin (few nanometer) polymer spacer layer is softened by local optical heating and restructured by strong capillary forces, which increase the gap between the plasmonic metal components. This results in a continuous blue-shift of the coupled plasmon from near infrared to visible with a tuning range of >150 nm that can be tightly controlled by adjusting either irradiation time or power.
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