AI Article Synopsis
- - The structure of the compound [Fe(C5H5)(C8H13N)](HC2O4) features separate cations and anions, specifically (ferrocenylmethyl)dimethylammonium cations and hydrogen oxalate anions.
- - The hydrogen oxalate anions form strong O-H⋯O hydrogen bonds that create linear chains parallel to the [100] direction, while the cations use bifurcated N-H⋯(O,O') interactions to connect with the anions.
- - Additionally, there are weaker C-H⋯π interactions between the ferrocenyl groups of neighboring cations present in the structure.
Article Abstract
The crystal structure of the title salt, [Fe(C5H5)(C8H13N)](HC2O4), consists of discrete (ferrocenylmeth-yl)di-methyl-ammonium cations and hydrogen oxalate anions. The anions are connected through a strong O-H⋯O hydrogen bond, forming linear chains running parallel to [100]. The cations are linked to the anions through bifurcated N-H⋯(O,O') hydrogen bonds. Weak C-H⋯π inter-actions between neighbouring ferrocenyl moieties are also observed.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571364 | PMC |
| http://dx.doi.org/10.1107/S205698901501333X | DOI Listing |
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