We numerically investigate quantum quenches of a nonintegrable hard-core Bose-Hubbard model to test the accuracy of the microcanonical ensemble in small isolated quantum systems. We show that, in a certain range of system size, the accuracy increases with the dimension of the Hilbert space D as 1/D. We ascribe this rapid improvement to the absence of correlations between many-body energy eigenstates. Outside of that range, the accuracy is found to scale either as 1/√D or algebraically with the system size.
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http://dx.doi.org/10.1103/PhysRevE.92.020102 | DOI Listing |
Phys Rev E
October 2024
Center for Quantum Technologies, Department of Physics, St. Kliment Ohridski University of Sofia, James Bourchier 5 Boulevard, 1164 Sofia, Bulgaria.
We investigate the onset of quantum thermalization in a system governed by the Jahn-Teller Hamiltonian, which describes the interaction between a single spin and two bosonic modes. We find that the Jahn-Teller model exhibits a finite-size quantum phase transition between the normal phase and two types of super-radiant phase when the ratios of spin-level splitting to each of the two bosonic frequencies grow to infinity. We test the prediction of the eigenstate thermalization hypothesis in the Jahn-Teller model.
View Article and Find Full Text PDFEntropy (Basel)
September 2024
Laboratoire de Physique Théorique, Université de Toulouse, CNRS, UPS, 31062 Toulouse, France.
J Chem Phys
September 2024
Department of Chemical and Biomedical Engineering, Cleveland State University, Cleveland, Ohio 44115, USA.
A novel statistical mechanical methodology is applied to clusters of N ≤ 7 atoms. Exact statistical analogs for any energy derivative of entropy ∂mS/∂Em are used in rigorous microcanonical Monte Carlo simulations to vastly enlarge the pool of measurable thermodynamic properties relative to previous work. All analogs are given for two alternative partition functions of the microcanonical ensemble.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2024
Department of Chemical Engineering, Indian Institute of Science, Bengaluru, Karnataka 560012, India.
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs' volume entropy. Both entropies have shortcomings─while Boltzmann entropy predicts unphysical negative/infinite absolute temperatures for small systems with an unbounded energy spectrum, Gibbs entropy entirely disallows negative absolute temperatures, in disagreement with experiments.
View Article and Find Full Text PDFPhys Rev Lett
August 2024
SISSA and INFN Sezione di Trieste, Via Bonomea 265, I-34136 Trieste, Italy and Istituto dei Sistemi Complessi, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy.
Ensemble inequivalence, i.e., the possibility of observing different thermodynamic properties depending on the statistical ensemble which describes the system, is one of the hallmarks of long-range physics, which has been demonstrated in numerous classical systems.
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