A general approach to fabricate nanowires based inorganic/organic composite flexible thermoelectric fabric using a simple and efficacious five-step vacuum filtration process is proposed. As an excellent example, the performance of freestanding flexible thermoelectric thin film using copper telluride nanowires/polyvinylidene fluoride (Cu1.75Te NWs/PVDF = 2:1) as building block is demonstrated. By burying the Cu1.75Te NWs into the PVDF polymer agent, the flexible fabric exhibits room-temperature Seebeck coefficient and electric conductivity of 9.6 μV/K and 2490 S/cm, respectively, resulting in a power factor of 23 μW/(mK(2)) that is comparable to the bulk counterpart. Furthermore, this NW-based flexible fabric can endure hundreds of cycles of bending tests without significant performance degradation.
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http://dx.doi.org/10.1021/acsami.5b07144 | DOI Listing |
ACS Appl Electron Mater
December 2024
Department of Electronics and Computer Science, University of Granada, Granada 18071, Spain.
In the evolution of pervasive electronics, it is imperative to significantly reduce the energy consumption of power systems and embrace sustainable materials and fabrication processes with minimal carbon footprint. Within this context, thermoelectric generators (TEGs) have garnered substantial attention in recent years because of the readily available thermal gradients in the environment, making them a promising energy-harvesting technology. Current commercial room-temperature thermoelectrics are based on scarce, expensive, and/or toxic V-VI chalcogenide materials, which limit their widespread use.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Institute of Chemical Engineering Sciences, Foundation of Research and Technology- Hellas (FORTH/ICE-HT), Stadiou Street, Platani, Patras 26504, Greece.
Due to their outstanding electrical and thermal properties, graphene and related materials have been proposed as ideal candidates for the development of lightweight systems for thermoelectric applications. Recently, the nanolaminate architecture that entails alternation of continuous graphene monolayers and ultrathin polymer films has been proposed as an efficient route for the development of composites with impressive physicochemical properties. In this work, we present a novel layer-by-layer approach for the fabrication of highly ordered, flexible, heat-resistant, and electrically conductive freestanding graphene/polymer nanolaminates through alternating Marangoni-driven self-assembly of reduced graphene oxide (rGO) and poly(ether imide) (PEI) films.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Flexible Sensing Technology, Institute of Chemical Engineering, Guangdong Academy of Sciences, Guangzhou 510665, China.
The global solar market is booming with a rapid growth in installed integrated devices, while photovoltaic (PV) systems are suffering from waste heat, which causes the decline of the photovoltaic conversion efficiency (PCE). This study presents the seamless integration of the ionic thermoelectric generator (iTEG) layer with traditional PV modules, facilitating the exploitation of waste heat and augmenting the overall power output. Experimental results validate the effectiveness of the iTEG, demonstrating substantial power generation and a consistent energy output.
View Article and Find Full Text PDFNanomicro Lett
December 2024
Department of Materials Science, Fudan University, Shanghai, 200433, People's Republic of China.
Emerging two-dimensional MXenes have been extensively studied in a wide range of fields thanks to their superior electrical and hydrophilic attributes as well as excellent chemical stability and mechanical flexibility. Among them, the ultrahigh electrical conductivity (σ) and tunable band structures of benchmark TiCT MXene demonstrate its good potential as thermoelectric (TE) materials. However, both the large variation of σ reported in the literature and the intrinsically low Seebeck coefficient (S) hinder the practical applications.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
IFIMUP Physics for Advanced Materials, Nanotechnology and Photonics, Department of Physics and Astronomy, Faculty of Sciences, University of Porto, Rua do Campo Alegre, Porto, 4169-007, Portugal.
In recent advancements within sensing technology, driven by the Internet of Things (IoT), significant impacts are observed on health sector applications, notably through wearable electronics like electronic tattoos (e-tattoos). These e-tattoos, designed for direct contact with the skin, facilitate precise monitoring of vital physiological parameters, including body heat, a critical indicator for conditions such as inflammation and infection. Monitoring these indicators can be crucial for early detection of chronic conditions, steering toward proactive healthcare management.
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