AI Article Synopsis
- Two new types of manganese phosphate oxalates were created without using solvents, showcasing environmentally friendly synthesis.
- These compounds feature unique three-dimensional structures based on a specific connectivity known as (4,6)-connected fsh topology.
- Interestingly, the presence of amine molecules alters how the metal phosphate and metal oxalate components contribute to building the overall structure of these frameworks.
Article Abstract
Two new organically templated manganese phosphate oxalates were synthesized under solvent-free conditions. They have different three-dimensional structures with a (4,6)-connected fsh topology. It is interesting that the amine molecules can reverse the structure-building roles of the metal phosphate skeleton and metal oxalate substructure for formation of their fsh-type frameworks.
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| http://dx.doi.org/10.1021/acs.inorgchem.5b01569 | DOI Listing |
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