The study embraces the shops: metallurgic, electrolysis, production of sulfuric acid and shop 100. Tests are performed on the environmental pollution by dust, sulfur dioxide, chlorine, aerosols of sulfuric acid, carbon monoxide, nitric oxide and dioxide, hydrogen chloride, arsenic (II) oxide (III), selenium, tellurium and metal aerosols: lead, copper, cadmium and zinc. The total concentrations of chemical noxae, generating multicomponent mixtures with one-way effect on the work place, are reckon, and estimation in the Bulgarian Institute of Hygiene and Occupational Health and the Ministry of public health methods. In the same shop is comprised a representative group of workers with paraclinical tests: GOT and GPT activity, content of copper and zinc in blood. The assessment made on the work conditions and the changes already found in the workers lead to a discussion for optimizing the conditions in the new shops for copper production.

Download full-text PDF

Source

Publication Analysis

Top Keywords

sulfuric acid
8
[hygienic evaluation
4
evaluation effects
4
effects toxic
4
toxic factors
4
factors work
4
work environment
4
environment copper-processing
4
copper-processing plants]
4
plants] study
4

Similar Publications

The present study exami-ned bacteria that anaerobically degrade the aromatic compound, benzoate, and obtained enrichment cultures from marine sediments under illumination. The enrichment culture contained anoxygenic photosynthetic bacteria and non-photosynthetic bacteria. The photosynthetic strain PS1, a purple sulfur bacterium in the genus Marichromatium, was unable to utilize benzoate; however, when combined with the non-photosynthetic bacterial isolate, Marinobacterium sp.

View Article and Find Full Text PDF

This study investigated the suitability of readily available and naturally occurring sources of microorganisms (inoculum) to use for the cultivation of sulphate-reducing bacteria (SRB) for acid mine drainage (AMD) remediation. The selected inocula included AMD water (AMD), mud (MUD) and reed-bed mud (RM) from the AMD surrounds, mealworms (MW), cow dung (CD) and raw sewage sludge (RS). The suitability of the different inoculum sources was evaluated by comparing the SO reduction and sulfide (S) production rates at three different pHs.

View Article and Find Full Text PDF

Persulfate-based advanced oxidation processes (PS-AOPs) catalyzed by carbon-based catalysts are promising for removing organic pollutants via radical/non-radical pathways. However, the activation efficiency of peroxymonosulfate (PMS) or peroxydisulfate (PDS) usage and the reaction mechanism remain insufficiently understood. In this study, the effects of PMS/PDS dosage on the degradation of bisphenol A (BPA, 10 mg/L) were evaluated using N-doped biochar (N-BC, 0.

View Article and Find Full Text PDF

Toward zero liquid discharge treatment of semiconductor wastewaters with a hybrid system integrating forward osmosis and multi-stage nanofiltration.

Water Res

February 2025

Department of Civil, Environmental and Architectural Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Republic of Korea. Electronic address:

The semiconductor industry produces large quantities of acidic wastewaters containing high levels of hydrofluoric acid (HF) and sulfuric acid (HSO), which poses severe environmental concern. Zero liquid discharge (ZLD) treatment of these wastewaters is a pressing need for sustainable growth of the semiconductor industry. Herein, we propose an innovative membrane-based hybrid system that combines forward osmosis (FO) with multi-stage NF process for simultaneous treatments of HSO and HF wastewaters.

View Article and Find Full Text PDF

Alkaline hydrolysis of 1,3,5-trichloro-2,4,6-trinitrobenzene (TCTNB) during spent sulfuric acid neutralization using lime.

Water Res

March 2025

Center for Environmental Systems, Department of Civil Environmental and Ocean Engineering, Stevens Institute of Technology; Hoboken, New Jersey, 07030, USA. Electronic address:

1,3,5-trichloro-2,4,6-trinitrobenzene (TCTNB) is the main byproduct of synthesizing an insensitive explosive 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) and requires environmental management and safe handling during disposal. This study introduces a lime neutralization method for treating TCTNB-containing spent sulfuric acid and systematically investigates the underlying hydrolysis mechanism using mass spectroscopy, Fourier transform infrared spectroscopy (FTIR) and Density functional theory (DFT) calculations. Our results demonstrated that TCTNB hydrolysis was significantly accelerated by increasing the pH from 10 to 12 and the temperature from 22 to 95 °C.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!