Dinitrogen complexes of the type Tp(R,R)Cr-N2-CrTp(R,R) are not the most labile precursors for Cr(i) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex - Tp(tBu,Me)Cr(η(2)-C2(SiMe3)2) - proved to be much more reactive.
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| http://dx.doi.org/10.1039/c5cc05993c | DOI Listing |
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