We investigate the impact of strained nanobubbles on the conductance characteristics of graphene nanoribbons using a combined molecular dynamics - tight-binding simulation scheme. We describe in detail how the conductance, density of states, and current density of zigzag or armchair graphene nanoribbons are modified by the presence of a nanobubble. In particular, we establish that low-energy electrons can be confined in the vicinity of or within the nanobubbles by the delicate interplay among the pseudomagnetic field pattern created by the shape of the bubble, mode mixing, and substrate interaction. The coupling between confined evanescent states and propagating modes can be enhanced under different clamping conditions, which translates into Fano resonances in the conductance traces.
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http://dx.doi.org/10.1039/c5nr03393d | DOI Listing |
J Am Chem Soc
November 2024
School of Materials Science and Engineering, Nanyang Technological University, 639798 Singapore.
Strain engineering plays a crucial role in activating the basal plane of the TMD catalysts. However, experimental evidence linking strain strength to activity and distinguishing effects of compressive and tensile strain remains elusive due to the absence of high-resolution correlation techniques. Here, we utilize nanobubble imaging by on-chip total-internal reflection microscopy to visualize active sites on the basal plane of strained MoS during hydrogen evolution reaction and atomic force microscopy to correlatively capture the nanoscale morphology and strain maps.
View Article and Find Full Text PDFAdv Mater
August 2024
State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
Collective excitations including plasmons, magnons, and layer-breathing vibration modes emerge at an ultralow frequency (<1 THz) and are crucial for understanding van der Waals materials. Strain at the nanoscale can drastically change the property of van der Waals materials and create localized states like quantum emitters. However, it remains unclear how nanoscale strain changes collective excitations.
View Article and Find Full Text PDFPhys Chem Chem Phys
February 2017
Department of Physics and Astronomy, University College London, Gower Street, London, WC1E 6BT, UK.
Exotic domain morphologies in ferroic materials are an exciting avenue for the development of novel nanoelectronics. In this work we have used large scale molecular dynamics to construct a strain-temperature phase diagram of the domain morphology of PbTiO ultrathin films. Sampling a wide interval of strain values over a temperature range up to the Curie temperature T, we found that epitaxial strain induces the formation of a variety of closure- and in-plane domain morphologies.
View Article and Find Full Text PDFNanoscale
October 2015
MackGraphe - Graphene and Nano-Materials Research Center, Mackenzie Presbyterian University, Rua da Consolação 896, 01302-907, São Paulo, SP, Brazil.
We investigate the impact of strained nanobubbles on the conductance characteristics of graphene nanoribbons using a combined molecular dynamics - tight-binding simulation scheme. We describe in detail how the conductance, density of states, and current density of zigzag or armchair graphene nanoribbons are modified by the presence of a nanobubble. In particular, we establish that low-energy electrons can be confined in the vicinity of or within the nanobubbles by the delicate interplay among the pseudomagnetic field pattern created by the shape of the bubble, mode mixing, and substrate interaction.
View Article and Find Full Text PDFNat Commun
February 2013
Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki, Japan.
The charge carriers in graphene are massless Dirac fermions and exhibit a relativistic Landau-level quantization in a magnetic field. Recently, it has been reported that, without any external magnetic field, quantized energy levels have been also observed from strained graphene nanobubbles on a platinum surface, which were attributed to the Landau levels of massless Dirac fermions in graphene formed by a strain-induced pseudomagnetic field. Here we show the generation of the Landau levels of massless Dirac fermions on a partially potassium-intercalated graphite surface without applying external magnetic field.
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