The thermal dimerization of three [n]cumulenes (n = 5, 7, and 9) has been investigated, and a common reactivity pattern is observed that gives radialenes and expanded radialenes through regioselective cycloaddition reactions; all three products are characterized using X-ray crystallography.
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| http://dx.doi.org/10.1039/c5cc05679a | DOI Listing |
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