Multiferroics were considered to be rare because magnetism and ferroelectricity require entirely different criteria for the materials. Several multiferroic oxides have, however, been discovered in the past few years by virtue of novel operating mechanisms, the most effective one being ferroelectricity driven by magnetism itself. Many such oxides where the magnetic and electric order parameters interact also exhibit magnetoelectric or magnetodielectric properties. In this Perspective, properties of manganites, ferrites, and other monophasic multiferroic oxides with spin-induced electric polarization are described. Multiferroic properties arising from charge ordering are examined. The present status of BiMnO3, which is an unusual example of a ferromagnetic-ferroelectric, is presented. Recent findings suggest that it is likely that many more multiferroic and magnetoelectric oxide materials exhibiting magnetically induced ferroelectricity will be found in the future.
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http://dx.doi.org/10.1021/jz300688b | DOI Listing |
Nano Lett
January 2025
Department of Physics, Washington University in St. Louis, St. Louis, Missouri 63130, United States.
Recent studies have demonstrated the ability to switch weakly coupled interlayer magnetic orders by using electric polarization in insulating van der Waals heterostructures. However, controlling strongly coupled intralayer magnetic orders remains a significant challenge. In this work, we propose that frustrated multiferroic heterostructures can exhibit enhanced intralayer magnetoelectric coupling.
View Article and Find Full Text PDFACS Nano
January 2025
School of Chemistry, Beihang University, Beijing 100191, China.
Two-dimensional (2D) ferromagnetic materials are subjects of intense research owing to their intriguing physicochemical properties, which hold great potential for fundamental research and spintronic applications. Specifically, 2D van der Waals (vdW) ferromagnetic materials retain both structural integrity and chemical stability even at the monolayer level. Moreover, due to their atomic thickness, these materials can be easily manipulated by stacking them with other 2D vdW ferroic and nonferroic materials, enabling precise control over their physical properties and expanding their functional applications.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA.
Two-dimensional (2D) materials that exhibit spontaneous magnetization, polarization, or strain (referred to as ferroics) have the potential to revolutionize nanotechnology by enhancing the multifunctionality of nanoscale devices. However, multiferroic order is difficult to achieve, requiring complicated coupling between electron and spin degrees of freedom. We propose a universal method to engineer multiferroics from van der Waals magnets by taking advantage of the fact that changing the stacking between 2D layers can break inversion symmetry, resulting in ferroelectricity as well as magnetoelectric coupling.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Minjiang Collaborative Center for Theoretical Physics, College of Physics and Electronic Information Engineering, Minjiang University, Fuzhou 350108, China.
Complex functional materials are characterized by intricate and competing bond orders, making them an excellent platform for evaluating the newly developed strongly constrained and appropriately normed (SCAN) density functional. In this study, we explore the effectiveness of SCAN in simulating the electronic properties of displacive ferroelectrics (BaTiO3 and PbTiO3) and magnetoelectric multiferroics (BiFeO3 and YMnO3), which encompass a broad spectrum of bonding characteristics. Due to a significant reduction in self-interaction error, SCAN manifests its improvements over the Perdew-Burke-Ernzerhof (PBE) method in three aspects: SCAN predicts more accurate ionicity, produces more compact orbitals, and better captures d-orbital anisotropy.
View Article and Find Full Text PDFSci Adv
January 2025
2D Crystal Consortium, Materials Research Institute, The Pennsylvania State University, University Park, PA 16802, USA.
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