A PtCl2(bpy) derivative tethered to two viologen (MV(2+)) moieties drives photochemical H2 evolution via forming a three-electron-reduced species possessing a bpy(-)˙-based (or MV(0)-based) reducing equivalent. Such species can only form after one electron reduction of both the MV(2+) sites because of rapid intramolecular electron transfer from bpy(-)˙ to MV(2+).
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| http://dx.doi.org/10.1039/c5cc03558a | DOI Listing |
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