Crystal structure of (6-bromo-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodi-thio-ate.

Acta Crystallogr E Crystallogr Commun

Department of Physics, Yuvaraja's College (Constituent College), University of Mysore, Mysore 570 005, Karnataka, India.

Published: July 2015

In the title compound, C15H14BrNO3S2, the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.034 (2) Å, and the morpholine ring adopts a chair conformation. The dihedral angle between best plane through the 2H-chromene ring system and the morpholine ring is 86.32 (9)°. Intra-molecular C-H⋯S hydrogen bonds are observed. In the crystal, inversion-related C-H⋯S and C-H⋯O inter-actions generate R 2 (2)(10) and R 2 (2)(8) rings patterns, respectively. In addition, the crystal packing features π-π inter-actions between fused benzene rings [centroid-centroid distance = 3.7558 (12) Å].

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518962PMC
http://dx.doi.org/10.1107/S2056989015011007DOI Listing

Publication Analysis

Top Keywords

2h-chromene ring
8
ring system
8
morpholine ring
8
crystal structure
4
structure 6-bromo-2-oxo-2h-chromen-4-ylmethyl
4
6-bromo-2-oxo-2h-chromen-4-ylmethyl morpholine-4-carbodi-thio-ate
4
morpholine-4-carbodi-thio-ate title
4
title compound
4
compound c15h14brno3s2
4
c15h14brno3s2 2h-chromene
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!