The lack of a simple analytical description of the hard-sphere fluid in a matrix with hard-core obstacles is limiting progress in the development of thermodynamic perturbation theories for the fluid in random porous media. We propose a simple and highly accurate analytical scheme, which allows us to calculate thermodynamic and percolation properties of a network-forming fluid confined in the random porous media, represented by the hard-sphere fluid and overlapping hard-sphere matrices, respectively. Our scheme is based on the combination of scaled-particle theory, Wertheim's thermodynamic perturbation theory for associating fluids and extension of the Flory-Stockmayer theory for percolation. The liquid-gas phase diagram and percolation threshold line for several versions of the patchy colloidal fluid model confined in a random porous media are calculated and discussed. The method presented enables calculation of the thermodynamic and percolation properties of a large variety of polymerizing and network-forming fluids confined in random porous media.
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Polymers (Basel)
December 2024
Membrane Institute, Kuban State University, 149, Stavropolskaya Str., 350040 Krasnodar, Russia.
The relevance of the hemodialysis procedure is increasing worldwide due to the growing number of patients suffering from chronic kidney disease. Taking into account the structure of dialysis polymer membranes is an important aspect in their development to achieve the required performance of hemodialyzers. We propose a new mathematical model of mass transfer that allows hollow-fiber membrane structural parameters to be taken into account in simulating the clearance () of hemodialyzers in a way that does not require difficult to achieve close approximation to the exact geometry of the membrane porous structure.
View Article and Find Full Text PDFFront Med (Lausanne)
December 2024
Department of Orthopedics, Tongren Hospital, Shanghai Jiao Tong University School of Medicine, Shanghai, China.
Phys Rev E
November 2024
Sonny Astani Department of Civil and Environmental Engineering, University of Southern California, Los Angeles, California 90089-2531, USA.
Statistics of diffusion, modeled by random walks, such as the mean number of distinct sites visited S(t) at time t, the mean probability P_{0}(t) of being at the origin of the walk, and the mean-squared displacements 〈R^{2}(t)〉 of the random walkers have been studied extensively in the past in both regular lattices and such disordered media as percolation clusters and other fractal structures, and universal power laws for such quantities have been derived. S(t) provides insight into reaction properties of geological formations, while P_{0}(t) is directly linked with the problem of back diffusion in remediation of groundwater aquifers. In all such studies, it was assumed that the conductances of the bonds that connect nearest-neighbor sites of the lattices are equal.
View Article and Find Full Text PDFArch Orthop Trauma Surg
December 2024
Joint Replacement Center, Eunpyeong St. Mary's Hospital, Seoul, 03312, Republic of Korea.
Introduction: With the advancement of porous surface processing technology, cementless total knee arthroplasty (TKA) has once again garnered attention. Cementless TKA lacks cement sealing, raising concerns regarding potential blood loss. Recently, patient blood management (PBM) protocols have been introduced to mitigate postoperative blood loss and transfusions.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
December 2024
Department of Earth and Environmental Sciences, College of Science and Engineering, University of Minnesota, Minneapolis, MN 55455.
Solute transport and biogeochemical reactions in porous and fractured media flows are controlled by mixing, as are subsurface engineering operations such as contaminant remediation, geothermal energy production, and carbon sequestration. Porous media flows are generally regarded as slow, so the effects of fluid inertia on mixing and reaction are typically ignored. Here, we demonstrate through microfluidic experiments and numerical simulations of mixing-induced reaction that inertial recirculating flows readily emerge in laminar porous media flows and dramatically alter mixing and reaction dynamics.
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