Pyroelectric harvesters convert time-dependent temperature variations into electric current. The appropriate geometry of the pyroelectric cells, coupled with the optimal period of temperature fluctuations, is key to driving the optimal load resistance, which enhances the performance of pyroelectric harvesters. The induced charge increases when the thickness of the pyroelectric cells decreases. Moreover, the induced charge is extremely reduced for the thinner pyroelectric cell when not used for the optimal period. The maximum harvested power is achieved when a 100 μm-thick PZT (Lead zirconate titanate) cell is used to drive the optimal load resistance of about 40 MΩ. Moreover, the harvested power is greatly reduced when the working resistance diverges even slightly from the optimal load resistance. The stored voltage generated from the 75 μm-thick PZT cell is less than that from the 400 μm-thick PZT cell for a period longer than 64 s. Although the thinner PZT cell is advantageous in that it enhances the efficiency of the pyroelectric harvester, the much thinner 75 μm-thick PZT cell and the divergence from the optimal period further diminish the performance of the pyroelectric cell. Therefore, the designers of pyroelectric harvesters need to consider the coupling effect between the geometry of the pyroelectric cells and the optimal period of temperature fluctuations to drive the optimal load resistance.
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http://dx.doi.org/10.3390/s150819633 | DOI Listing |
Chem Sci
January 2025
Department of Chemistry, National Tsing Hua University Hsinchu 300044 Taiwan
PbZrTiO cubes with tunable sizes and cuboids have been hydrothermally synthesized. PbZrTiO cubes with three different Zr : Ti atomic percentages were also prepared. Analysis of synchrotron X-ray diffraction (XRD) patterns reveals the presence of two lattice components for these samples.
View Article and Find Full Text PDFNat Commun
January 2025
CAS Center for Excellence in Nanoscience, Beijing Key Laboratory of Micro-Nano Energy and Sensor, Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing, 101400, PR China.
The coupling of photovoltaic and pyroelectric effects is a common phenomenon in ferroelectric films and often results in coupling enhancements. Although the coupling effects of a variety of ferroelectric films have been examined in terms of improved performance, they have yet to be quantitatively ranked and assessed. Here, by taking the charge coupling factor, the Yang's charge, and output energy as metrics to evaluate the coupling performance, a methodology is developed for evaluating the performance of a range ferroelectric films when the pyroelectric and photovoltaic effects are coupled.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Portici Research Centre, ENEA-Italian National Agency for New Technologies, Energy and Sustainable Economic Development, 80055 Portici, Italy.
Polyvinylidene fluoride (PVDF)-based materials are the most researched polymers in the field of energy harvesting. Their production in thin-film form through printing technologies can potentially offer several manufacturing and performance advantages, such as low-cost, low-temperature processing, use of flexible substrates, custom design, low thermal inertia and surface-scaling performance. However, solution-based processes, like printing, miss fine control of the microstructure during film-forming, making it difficult to achieve a high level of polarization, necessary for PVDF to exhibit electroactive characteristics.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, Maharashtra, India.
Transforming abundant thermal energy into electrical energy is an essential and sustainable solution to meet the rapidly growing global energy demand. In this communication, we report an electrical poling-free molecular complex [Zn(bpy)](ClO)·HO (1) with an appreciable pyroelectric coefficient value of 25 μC m K. This allowed us to harvest waste heat energy using a pyroelectric nanogenerator (PyG) device of 1, a relatively unexplored area for molecular complexes.
View Article and Find Full Text PDFMater Horiz
December 2024
Quantum Materials and Devices Unit, Institute of Nano Science and Technology, Knowledge City, Sector 81, Mohali 140306, India.
The 'pyro-phototronic effect' plays a nontrivial role in advancing ferroelectric (FE) devices of light detectors, light-emitting diodes, and other smart technologies. In this work, a premier FE copolymer, poly(vinylidene fluoride--trifluoro ethylene) (P(VDF-TrFE)), is reinforced with a lead-free double perovskite, CsSnI, to render profound properties in a hybrid nanostructure. It presents a unique example of the coupling of ferro-, pyro- and piezo-electrics to the 'photoexcitation' of exotic charges that actively empower the synergetic features.
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