Lead recovery from scrap cathode ray tube funnel glass by hydrothermal sulphidisation.

Waste Manag Res

Shanghai Xin Jinqiao Environmental Protection Company, Shanghai, China.

Published: October 2015

AI Article Synopsis

  • The research explored using a hydrothermal sulphidisation method to effectively separate lead from scrap cathode ray tube funnel glass.
  • Prior to this process, the glass underwent mechanical activation to enhance the reaction with water, generating hydroxyl ions that facilitated the conversion of lead to lead sulphide.
  • The study found that increasing temperatures significantly improved sulphidisation rates, reaching 100% efficiency after 8 hours at 300°C.

Article Abstract

This research focused on the application of the hydrothermal sulphidisation method to separate lead from scrap cathode ray tube funnel glass. Prior to hydrothermal treatment, the cathode ray tube funnel glass was pretreated by mechanical activation. Under hydrothermal conditions, hydroxyl ions (OH(-)) were generated through an ion exchange reaction between metal ions in mechanically activated funnel glass and water, to accelerate sulphur disproportionation; no additional alkaline compound was needed. Lead contained in funnel glass was converted to lead sulphide with high efficiency. Temperature had a significant effect on the sulphidisation rate of lead in funnel glass, which increased from 25% to 90% as the temperature increased from 100 °C to 300 °C. A sulphidisation rate of 100% was achieved at a duration of 8 h at 300 °C. This process of mechanical activation and hydrothermal sulphidisation is efficient and promising for the treatment of leaded glass.

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Source
http://dx.doi.org/10.1177/0734242X15597777DOI Listing

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