This study compared the granulometric properties, mineralogical composition and concentrations of major and trace element oxides of commonly ingested soils (geophagic soil) collected from different countries with a view of understanding how varied they may be in these properties and to understand the possible health implications of ingesting them. Soil samples were collected from three different countries (South Africa, Swaziland and Democratic Republic of Congo (DRC)) and their granulometric properties, concentrations of major and trace element oxides as well as mineralogical composition determined. Differences were observed in the granulometric properties of geophagic soil from the three different countries with most of them having <20% clay content. The soils also showed varied degrees of weathering with values of Chemical Index of Alteration (CIA) and Chemical Index of Weathering (CIW) being between 60% and 99.9% respectively. The mineral assemblages of the soils from South Africa and Swaziland were dominated by the primary minerals quartz and feldspar whereas soils from DRC had more of kaolinite, a secondary mineral than primary minerals. Soils from DRC were associated with silt, clay, Al2O3, and CIA unlike most samples from South Africa which were associated with SiO2, sand, K2O, CaO, and MgO. The soils from Swaziland were closely associated with silt, H2O and Fe2O3(t). These associations reflect the mineralogy of the samples. These soils are not likely to serve as nutrient supplements because of the low concentrations of the nutrient elements contained. The coarse texture of the samples may also result in dental destruction during mastication. Sieving of the soils before ingestion to remove coarse particles is recommended to reduce the potential health threat associated with the ingestion of coarse-textured soils.
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http://dx.doi.org/10.3390/ijerph120808933 | DOI Listing |
JAMA Surg
March 2025
Department of Gastric Surgery, Fujian Medical University Union Hospital, Fuzhou, China.
Importance: Indocyanine green (ICG)-guided lymphadenectomy has been increasingly used to treat gastric cancer. However, its oncologic impact remains unclear.
Objective: To investigate the effect of ICG tracing on long-term outcomes in patients diagnosed with locally advanced gastric cancer undergoing neoadjuvant chemotherapy (NAC) followed by laparoscopic radical gastrectomy.
Dalton Trans
March 2025
Institute of Chemistry, University of Kassel, Heinrich-Plett-Straße 40, 34132 Kassel, Germany.
[FeCp*{N(SiMe)}] is a high-spin complex with four unpaired electrons according to SQUID magnetometry and Mößbauer spectroscopy. Its reactions with 4-dimethylaminopyridine (DMAP) and NPrX (X = Cl, Br) respectively afford [FeCp*{N(SiMe)}(DMAP)] (6), NBu[FeCp*Cl{N(SiMe)}] (7), and NPr[FeCp*Br{N(SiMe)}] (8). 7 and 8 react with formamidinium tetrafluoroborates fc[(NCHR)CH][BF] (fc = 1,1'-ferrocenylene; R = Ph, Mes) at room temperature in THF to furnish [FeCp*X{fc[(NCHR)C]}] (4: X = Cl, R = Mes; 10: X = Br, R = Mes; 11: X = Cl, R = Ph; 12: X = Br, R = Ph), which contain a ferrocene-based NHC ligand.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, California 94720, United States.
Developing active, stable, and cost-effective acidic oxygen evolution reaction (OER) catalyst is a critical challenge in realizing large-scale hydrogen (H) production via electrochemical water splitting. Utilizing highly active and relatively inexpensive Ru is generally challenged by its long-term durability issue. Here, we explore the potential of stabilizing active Ru sites in Ru(Ir,Fe,Co,Ni) multicomponent alloy by investigating its phase formation behavior, OER performance, and OER-induced surface reconstruction.
View Article and Find Full Text PDFSci Rep
March 2025
Department of Environmental and Occupational Health, School of Public Health, Guangxi Medical University, Shuangyong Road No. 22, Nanning, 530021, Guangxi, PR China.
This study investigated the relationship between essential plasma metals (Co, Cr, Cu, Mn, Mo, Se, Zn) and telomere length in 2,194 Chinese adults aged ≥ 30 years. Metal concentrations were measured using ICP-MS, and leukocyte relative telomere length (rTL) was assessed by qPCR. In the elderly, Cr and Mn were significantly positively correlated with rTL, while Mo, Zn, and Cu showed negative correlations.
View Article and Find Full Text PDFCommun Earth Environ
March 2025
Transdisciplinary Science Group, Cawthron Institute, Nelson, New Zealand.
Agriculture and food systems are major sources of plastic pollution but they are also vulnerable to their diverse lifecycle impacts. However, this problem is not well-recognized in global policy and scientific discourse, agendas, and monitoring of food systems. The United Nations-led Global Plastics Treaty, which has been under negotiation since 2022, is a critical opportunity to address pollution across the entire plastics lifecycle for more sustainable and resilient food systems.
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