This paper introduced a process to prepare the carbon nanosphere (CNS)/NiCo2O4 core-shell sub-microspheres. That is: 1) CNSs were firstly prepared via a simple hydrothermal method; 2) a layer of NiCo2O4 precursor was coated on the CNS surface; 3) finally the composite was annealed at 350 °C for 2 hours in the air, and the CNS/NiCo2O4 core-shell sub-microspheres were obtained. This core-shell sub-microsphere was prepared with a simple, economical and environmental-friendly hydrothermal method, and was suitable for large-scale production, which expects a promising electrode candidate for high performance energy storage applications. Electrochemical experiments revealed that the composite exhibited remarkable electrochemical performances with high capacitance and desirable cycle life at high rates, such as: 1) the maximum specific capacitance was up to 1420 F/g at 1 A/g; 2) about 98.5% of the capacitance retained after 3000 charge-discharge cycles; 3) the capacitance retention was about 72% as the current density increase from 1 A/g to 10 A/g.
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http://dx.doi.org/10.1038/srep12903 | DOI Listing |
Chemosphere
March 2022
Key Laboratory of Photochemical Biomaterials and Energy Storage Materials, Heilongjiang, Harbin Normal University, Harbin, 150025, PR China; Province and Key Laboratory of Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin, 150025, PR China. Electronic address:
Reasonable doping is beneficial to the generation of defects, which is a feasibility strategy to improve the ZnO sensing performance. Herein, we presented an in situ self-sacrificing template strategy for fabricating Co doped h-ZnO core-shell structures (h-ZnO/ZnCo) with different defect contents, pyrolyzing hierarchical porous ZnO (h-ZnO) sub-microspheres coated by zeolite imidazolate frameworks (h-ZnO/ZIF-ZnCo). The investigations of X-ray photoelectron (XPS), photoluminescence (PL) and Raman spectra indicate that donor defects include zinc interstitial (Zn) and oxygen vacancy (V) in h-ZnO/ZnCo can be tuned by Co dopant (x = 0-30%).
View Article and Find Full Text PDFJ Control Release
October 2021
College of Pharmacy, Jiangsu University, Zhenjiang 212013, China. Electronic address:
Albumin nanoparticles represent an approved anti-tumor drug delivery system. However, there is only one albumin nanoparticle product (paclitaxel-albumin nanoparticle) on the market. The application of albumin carriers is limited by the lack of universal preparation technology and insufficient targeting effect.
View Article and Find Full Text PDFSci Rep
August 2015
1] Shenzhen Research Institute, Wuhan University, Shenzhen 518057, China [2] School of Physics and Technology, Wuhan University, Wuhan 430072, China.
Chem Asian J
June 2010
Nankai University, Tianjin 300071, P.R. China.
Magnetic silica-coated magnetite (Fe(3)O(4)) sub-microspheres with immobilized metal-affinity ligands are prepared for protein adsorption. First, magnetite sub-microspheres were synthesized by a hydrothermal method. Then silica was coated on the surface of Fe(3)O(4) particles using a sol-gel method to obtain magnetic silica sub-microspheres with core-shell morphology.
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