Well-defined palladium(ii) complexes for ligand-enabled C(sp(3))-alkynylation.

Dalton Trans

Catalysis Division, Dr. Homi Bhabha Road, CSIR-National Chemical Laboratory (CSIR-NCL), Pune 411008, India.

Published: September 2015

The first example of ligand-enabled C(sp(3))-alkynylation of 8-methylquinoline is reported. The reaction is catalysed by well-defined Pd(ii) complexes. The present C(sp(3))-alkynylation has a broad substrate scope as well as functional group tolerance and proceeds efficiently under mild conditions.

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http://dx.doi.org/10.1039/c5dt02772aDOI Listing

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