Chemically Altering the Solubility and Durability of Dyes for Sensitized Solar Cells.

By designing dyes with fluoroalkyl groups, the optical and electronic properties of the alkyl analogue were maintained while dramatically altering the solubility. Dyes, F-TABTA (8) and its masked derivative F-TABTSi (9), that enable them to be deposited under conventional organic solvent and scCO2 conditions, respectively, were developed. In liquid DSSC devices, the fluoroalkyl dye (F-TABTA, 8) performs slightly better than its alkyl analogue (D21L6, 10), and interestingly, it was found that the former device showed better stability over time. Deploying the silyl-masked precursor F-TABTSi (9), this dye was deposited onto TiO2 photoanodes from scCO2 in very short contact times (2.5 h), and ECEs of 7.70% were obtained that exceed the performance of the alkyl dye when deposited by conventional methods.